N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide

Hamad H. Al Mamari; Ahmed Al Sheidi

doi:10.3390/M1175

N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide

Hamad H. Al Mamari^*, Ahmed Al Sheidi

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

1 Citation (Scopus)

Abstract

In the present Short Note, we report a synthesis for the title compound, N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide by reacting 2-methylbenzoyl chloride (or 2-methylbenzoic acid) with 1-aminoanthraquinone. The synthesized target compound was fully characterized by various spectroscopic methods (¹H-NMR,¹³C-NMR, IR, GC-MS). The importance of this compound lies its possession of an N,O-bidentate directing group, potentially suitable for metal-catalyzed C-H bond functionalization reactions.

Original language	English
Article number	M1175
Pages (from-to)	1-5
Number of pages	5
Journal	MolBank
Volume	2020
Issue number	4
DOIs	https://doi.org/10.3390/M1175
Publication status	Published - 2020

Keywords

Benzamides
Bidentate directing groups
Bis-chelates
C-H bond functionalization
Chelation-assistance
Organic synthesis

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide",

abstract = "In the present Short Note, we report a synthesis for the title compound, N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide by reacting 2-methylbenzoyl chloride (or 2-methylbenzoic acid) with 1-aminoanthraquinone. The synthesized target compound was fully characterized by various spectroscopic methods (1H-NMR,13C-NMR, IR, GC-MS). The importance of this compound lies its possession of an N,O-bidentate directing group, potentially suitable for metal-catalyzed C-H bond functionalization reactions.",

keywords = "Benzamides, Bidentate directing groups, Bis-chelates, C-H bond functionalization, Chelation-assistance, Organic synthesis",

author = "{Al Mamari}, {Hamad H.} and Sheidi, {Ahmed Al}",

note = "Publisher Copyright: {\textcopyright} 2020 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2020",

doi = "10.3390/M1175",

language = "English",

volume = "2020",

pages = "1--5",

journal = "MolBank",

issn = "1422-8599",

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TY - JOUR

T1 - N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide

AU - Al Mamari, Hamad H.

AU - Sheidi, Ahmed Al

PY - 2020

Y1 - 2020

N2 - In the present Short Note, we report a synthesis for the title compound, N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide by reacting 2-methylbenzoyl chloride (or 2-methylbenzoic acid) with 1-aminoanthraquinone. The synthesized target compound was fully characterized by various spectroscopic methods (1H-NMR,13C-NMR, IR, GC-MS). The importance of this compound lies its possession of an N,O-bidentate directing group, potentially suitable for metal-catalyzed C-H bond functionalization reactions.

AB - In the present Short Note, we report a synthesis for the title compound, N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide by reacting 2-methylbenzoyl chloride (or 2-methylbenzoic acid) with 1-aminoanthraquinone. The synthesized target compound was fully characterized by various spectroscopic methods (1H-NMR,13C-NMR, IR, GC-MS). The importance of this compound lies its possession of an N,O-bidentate directing group, potentially suitable for metal-catalyzed C-H bond functionalization reactions.

KW - Benzamides

KW - Bidentate directing groups

KW - Bis-chelates

KW - C-H bond functionalization

KW - Chelation-assistance

KW - Organic synthesis

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U2 - 10.3390/M1175

DO - 10.3390/M1175

M3 - Comment/debate

AN - SCOPUS:85097506567

SN - 1422-8599

VL - 2020

SP - 1

EP - 5

JO - MolBank

JF - MolBank

IS - 4

M1 - M1175

ER -

N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide

Abstract

Keywords

ASJC Scopus subject areas

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