TY - JOUR
T1 - N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide
AU - Al Mamari, Hamad H.
AU - Sheidi, Ahmed Al
N1 - Funding Information:
Funding: The research work is funded by Sultan Qaboos University Internal Grant (IG/SCI/CHEM/15/02).
Publisher Copyright:
© 2020 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2020
Y1 - 2020
N2 - In the present Short Note, we report a synthesis for the title compound, N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide by reacting 2-methylbenzoyl chloride (or 2-methylbenzoic acid) with 1-aminoanthraquinone. The synthesized target compound was fully characterized by various spectroscopic methods (1H-NMR,13C-NMR, IR, GC-MS). The importance of this compound lies its possession of an N,O-bidentate directing group, potentially suitable for metal-catalyzed C-H bond functionalization reactions.
AB - In the present Short Note, we report a synthesis for the title compound, N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2-methylbenzamide by reacting 2-methylbenzoyl chloride (or 2-methylbenzoic acid) with 1-aminoanthraquinone. The synthesized target compound was fully characterized by various spectroscopic methods (1H-NMR,13C-NMR, IR, GC-MS). The importance of this compound lies its possession of an N,O-bidentate directing group, potentially suitable for metal-catalyzed C-H bond functionalization reactions.
KW - Benzamides
KW - Bidentate directing groups
KW - Bis-chelates
KW - C-H bond functionalization
KW - Chelation-assistance
KW - Organic synthesis
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U2 - 10.3390/M1175
DO - 10.3390/M1175
M3 - Comment/debate
AN - SCOPUS:85097506567
SN - 1422-8599
VL - 2020
SP - 1
EP - 5
JO - MolBank
JF - MolBank
IS - 4
M1 - M1175
ER -