A general method for the selective reduction of ketones in the presence of enones.

Dale E. Ward; Chung K. Rhee; Wajdi M. Zoghaib

doi:10.1016/S0040-4039(00)80137-9

A general method for the selective reduction of ketones in the presence of enones.

Dale E. Ward^*, Chung K. Rhee, Wajdi M. Zoghaib

^*المؤلف المقابل لهذا العمل

نتاج البحث: المساهمة في مجلة › Article › مراجعة النظراء

53 اقتباسات (Scopus)

ملخص

Ketones can be reduced in the presence of conjugated enones by sodiumborohydride in 50% methanol in dichloromethane at -78°C. The selectivity is generally excellent. In favorable cases the reaction can be carried out at room temperature in dichloromethane with acetic acid as catalyst.

اللغة الأصلية	English
الصفحات (من إلى)	517-520
عدد الصفحات	4
دورية	Tetrahedron Letters
مستوى الصوت	29
رقم الإصدار	5
المعرِّفات الرقمية للأشياء	https://doi.org/10.1016/S0040-4039(00)80137-9
حالة النشر	Published - 1988
منشور خارجيًا	نعم

ASJC Scopus subject areas

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الوصول إلى المستند

10.1016/S0040-4039(00)80137-9

الملفات والروابط الأخرى

Link to publication in Scopus

قم بذكر هذا

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title = "A general method for the selective reduction of ketones in the presence of enones.",

abstract = "Ketones can be reduced in the presence of conjugated enones by sodiumborohydride in 50% methanol in dichloromethane at -78°C. The selectivity is generally excellent. In favorable cases the reaction can be carried out at room temperature in dichloromethane with acetic acid as catalyst.",

author = "Ward, {Dale E.} and Rhee, {Chung K.} and Zoghaib, {Wajdi M.}",

note = "Funding Information: Acknowledgment: Financial support from the Natural Sciences and Engineering Research Council (Canada) and the University of Saskatchewan is gratefully acknowledged.",

year = "1988",

doi = "10.1016/S0040-4039(00)80137-9",

language = "English",

volume = "29",

pages = "517--520",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "5",

}

TY - JOUR

T1 - A general method for the selective reduction of ketones in the presence of enones.

AU - Ward, Dale E.

AU - Rhee, Chung K.

AU - Zoghaib, Wajdi M.

N1 - Funding Information: Acknowledgment: Financial support from the Natural Sciences and Engineering Research Council (Canada) and the University of Saskatchewan is gratefully acknowledged.

PY - 1988

Y1 - 1988

N2 - Ketones can be reduced in the presence of conjugated enones by sodiumborohydride in 50% methanol in dichloromethane at -78°C. The selectivity is generally excellent. In favorable cases the reaction can be carried out at room temperature in dichloromethane with acetic acid as catalyst.

AB - Ketones can be reduced in the presence of conjugated enones by sodiumborohydride in 50% methanol in dichloromethane at -78°C. The selectivity is generally excellent. In favorable cases the reaction can be carried out at room temperature in dichloromethane with acetic acid as catalyst.

UR - http://www.scopus.com/inward/record.url?scp=0001075632&partnerID=8YFLogxK

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U2 - 10.1016/S0040-4039(00)80137-9

DO - 10.1016/S0040-4039(00)80137-9

M3 - Article

AN - SCOPUS:0001075632

SN - 0040-4039

VL - 29

SP - 517

EP - 520

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 5

ER -

A general method for the selective reduction of ketones in the presence of enones.

ملخص

ASJC Scopus subject areas

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الملفات والروابط الأخرى

بصمة

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