Tuning the optical properties and photocatalytic activity of Ti0.96Nd0.02O2 by Cd/Fe co-doping

A. Mustafa, F. Bensouici*, M. Bououdina, M. Benyahkhlef, B. Al-Najar, T. Souier, B. Belache

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

This research work aims to investigate Fe/Nd and Cd/Nd co-doped TiO2 thin films prepared by sol–gel and deposited by dip-coating onto soda-lime glass and the impact of these dopants on the photocatalytic properties. The structural, optical, morphological, and photocatalytic properties of all the prepared samples have been characterized by X-ray diffraction, atomic force microscope, UV–Vis spectroscopy (UV–Vis), and photoluminescence spectroscopy. Rietveld analysis of XRD patterns indicates that TiO2 co-doping by Fe/Nd and Cd/Nd deteriorates the crystallinity of the pure anatase phase whereas the crystallite size seems not affected, i.e., 13 nm. The morphology of the surface has been affected; the roughness increases from 0.91 nm for pure TiO2 to 2.73 nm for Cd/Nd co-doped TiO2. UV–vis spectroscopy and photoluminescence analyses indicate that the band-gap energy decreases with co-doping from 3.33 eV for TiO2 up to 3.26 eV for Fe-Nd/TiO2. The degradation of methyl blue tests manifests that pure TiO2 exhibits higher efficiency of 89% dye in three hours only. Significant decrease in the photocatalytic activity upon co-doping has been observed and a mechanism based on the combined effect of doping, annealing, and substrate effect is proposed to explain the photodegradation behavior.

Original languageEnglish
Pages (from-to)5707-5719
Number of pages13
JournalJournal of Materials Science: Materials in Electronics
Volume33
Issue number8
DOIs
Publication statusPublished - Mar 2022
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

Cite this