TY - JOUR
T1 - Thermophysical Study of Binary Systems of tert-Amyl Methyl Ether with n-Hexane and m-Xylene
AU - Ahmad, Waqar
AU - Vakilinejad, Ali
AU - Aman, Zachary M.
AU - Vakili-Nezhaad, G. Reza
N1 - Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/2/14
Y1 - 2019/2/14
N2 - This work presents the experimentally determined density (?), viscosity (?), speed of sound (u), and surface tension (σ) data for tert-amyl methyl ether (TAME) + n-hexane and TAME + m-xylene systems at several temperatures (298.15, 308.15, 318.15, 323.15, and 328.15 K). These experimentally determined thermophysical data are utilized to compute various excess/deviation parameters such as molar volume (V E ), isentropic compressibility (?s E ), speed of sound (u E ), deviation in viscosity (? Ln ?), isobaric thermal expansion coefficient (αP E ), and surface tension (σ E ). The inspection of parameters response may interpret the existing specific molecular interactions as well as the mixing behavior of solutions. The critical analysis of observed parametric behavior have unveiled the strong and weak molecular interactions in TAME with m-xylene and TAME with n-hexane systems, respectively.
AB - This work presents the experimentally determined density (?), viscosity (?), speed of sound (u), and surface tension (σ) data for tert-amyl methyl ether (TAME) + n-hexane and TAME + m-xylene systems at several temperatures (298.15, 308.15, 318.15, 323.15, and 328.15 K). These experimentally determined thermophysical data are utilized to compute various excess/deviation parameters such as molar volume (V E ), isentropic compressibility (?s E ), speed of sound (u E ), deviation in viscosity (? Ln ?), isobaric thermal expansion coefficient (αP E ), and surface tension (σ E ). The inspection of parameters response may interpret the existing specific molecular interactions as well as the mixing behavior of solutions. The critical analysis of observed parametric behavior have unveiled the strong and weak molecular interactions in TAME with m-xylene and TAME with n-hexane systems, respectively.
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U2 - 10.1021/acs.jced.8b00589
DO - 10.1021/acs.jced.8b00589
M3 - Article
AN - SCOPUS:85062014917
SN - 0021-9568
VL - 64
SP - 459
EP - 470
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 2
ER -