The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe2O4

A. D. Al-Rawas; H. M. Widatallah; I. A. Al-Omari; C. Johnson; M. E. Elzain; A. M. Gismelseed; S. Al-Taie; A. A. Yousif

doi:10.1063/1.1923669

The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe₂O₄

A. D. Al-Rawas^*, H. M. Widatallah, I. A. Al-Omari, C. Johnson, M. E. Elzain, A. M. Gismelseed, S. Al-Taie, A. A. Yousif

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

4 Citations (Scopus)

Abstract

The influence of mechanical milling and subsequent calcination of a 1:1 molar mixture of CuO and α-Fe₂O₃ on the formation of CuFe₂O₄ has been investigated with X-ray powder diffraction (XRD) and Mössbauer spectroscopy. Pre-milling the mixture for 160h leads to the formation of CuFe₂O₄ nanocrystallites at 750°C. This temperature is ca. 400-450°C lower than the temperatures at which the material is conventionally prepared using the ceramic technique that involves no pre-milling of the reactants. Rietveld refinement of the XRD reveals the presence of both cubic and tetragonal crystal structures in the CuFe ₂O₄ obtained.

Original language	English
Title of host publication	INDUSTRIAL APPLICATIONS OF THE MOSSBAUER EFFECT
Subtitle of host publication	International Symposium on the Industrial Applications of the Mossbauer Effect
Pages	277-281
Number of pages	5
DOIs	https://doi.org/10.1063/1.1923669
Publication status	Published - Apr 26 2005
Externally published	Yes
Event	International Conference on the Industrial Applications of the Mossbauer Effect - Madrid, Spain Duration: Oct 4 2004 → Oct 8 2004

Publication series

Name	AIP Conference Proceedings
Volume	765
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Other

Other	International Conference on the Industrial Applications of the Mossbauer Effect
Country/Territory	Spain
City	Madrid
Period	10/4/04 → 10/8/04

ASJC Scopus subject areas

Physics and Astronomy(all)

Access to Document

10.1063/1.1923669

Cite this

Al-Rawas, A. D., Widatallah, H. M., Al-Omari, I. A., Johnson, C., Elzain, M. E., Gismelseed, A. M., Al-Taie, S., & Yousif, A. A. (2005). The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe₂O₄. In INDUSTRIAL APPLICATIONS OF THE MOSSBAUER EFFECT: International Symposium on the Industrial Applications of the Mossbauer Effect (pp. 277-281). (AIP Conference Proceedings; Vol. 765). https://doi.org/10.1063/1.1923669

The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe₂O₄. / Al-Rawas, A. D.; Widatallah, H. M.; Al-Omari, I. A.; Johnson, C.; Elzain, M. E.; Gismelseed, A. M.; Al-Taie, S.; Yousif, A. A.

INDUSTRIAL APPLICATIONS OF THE MOSSBAUER EFFECT: International Symposium on the Industrial Applications of the Mossbauer Effect. 2005. p. 277-281 (AIP Conference Proceedings; Vol. 765).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Al-Rawas, AD , Widatallah, HM , Al-Omari, IA, Johnson, C, Elzain, ME , Gismelseed, AM, Al-Taie, S & Yousif, AA 2005, The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe₂O₄. in INDUSTRIAL APPLICATIONS OF THE MOSSBAUER EFFECT: International Symposium on the Industrial Applications of the Mossbauer Effect. AIP Conference Proceedings, vol. 765, pp. 277-281, International Conference on the Industrial Applications of the Mossbauer Effect, Madrid, Spain, 10/4/04. https://doi.org/10.1063/1.1923669

Al-Rawas AD , Widatallah HM , Al-Omari IA, Johnson C, Elzain ME , Gismelseed AM et al. The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe₂O₄. In INDUSTRIAL APPLICATIONS OF THE MOSSBAUER EFFECT: International Symposium on the Industrial Applications of the Mossbauer Effect. 2005. p. 277-281. (AIP Conference Proceedings). https://doi.org/10.1063/1.1923669

Al-Rawas, A. D. ; Widatallah, H. M. ; Al-Omari, I. A. ; Johnson, C. ; Elzain, M. E. ; Gismelseed, A. M. ; Al-Taie, S. ; Yousif, A. A. / The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe₂O₄. INDUSTRIAL APPLICATIONS OF THE MOSSBAUER EFFECT: International Symposium on the Industrial Applications of the Mossbauer Effect. 2005. pp. 277-281 (AIP Conference Proceedings).

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title = "The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe2O4",

abstract = "The influence of mechanical milling and subsequent calcination of a 1:1 molar mixture of CuO and α-Fe2O3 on the formation of CuFe2O4 has been investigated with X-ray powder diffraction (XRD) and M{\"o}ssbauer spectroscopy. Pre-milling the mixture for 160h leads to the formation of CuFe2O4 nanocrystallites at 750°C. This temperature is ca. 400-450°C lower than the temperatures at which the material is conventionally prepared using the ceramic technique that involves no pre-milling of the reactants. Rietveld refinement of the XRD reveals the presence of both cubic and tetragonal crystal structures in the CuFe 2O4 obtained.",

author = "Al-Rawas, {A. D.} and Widatallah, {H. M.} and Al-Omari, {I. A.} and C. Johnson and Elzain, {M. E.} and Gismelseed, {A. M.} and S. Al-Taie and Yousif, {A. A.}",

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AU - Johnson, C.

AU - Elzain, M. E.

AU - Gismelseed, A. M.

AU - Al-Taie, S.

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AB - The influence of mechanical milling and subsequent calcination of a 1:1 molar mixture of CuO and α-Fe2O3 on the formation of CuFe2O4 has been investigated with X-ray powder diffraction (XRD) and Mössbauer spectroscopy. Pre-milling the mixture for 160h leads to the formation of CuFe2O4 nanocrystallites at 750°C. This temperature is ca. 400-450°C lower than the temperatures at which the material is conventionally prepared using the ceramic technique that involves no pre-milling of the reactants. Rietveld refinement of the XRD reveals the presence of both cubic and tetragonal crystal structures in the CuFe 2O4 obtained.

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