The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe2O4

A. D. Al-Rawas; H. M. Widatallah; I. A. Al-Omari; C. Johnson; M. E. Elzain; A. M. Gismelseed; S. Al-Taie; A. A. Yousif

doi:10.1063/1.1923669

The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe2O4

A. D. Al-Rawas^*, H. M. Widatallah, I. A. Al-Omari, C. Johnson, M. E. Elzain, A. M. Gismelseed, S. Al-Taie, A. A. Yousif

^*Corresponding author for this work

Physics

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

4 Citations (Scopus)

Abstract

The influence of mechanical milling and subsequent calcination of a 1:1 molar mixture of CuO and α-Fe₂O₃ on the formation of CuFe₂O₄ has been investigated with X-ray powder diffraction (XRD) and Mössbauer spectroscopy. Pre-milling the mixture for 160h leads to the formation of CuFe₂O₄ nanocrystallites at 750°C. This temperature is ca. 400-450°C lower than the temperatures at which the material is conventionally prepared using the ceramic technique that involves no pre-milling of the reactants. Rietveld refinement of the XRD reveals the presence of both cubic and tetragonal crystal structures in the CuFe ₂O₄ obtained.

Original language	English
Title of host publication	AIP Conference Proceedings
Pages	277-281
Number of pages	5
Volume	765
DOIs	https://doi.org/10.1063/1.1923669
Publication status	Published - Apr 26 2005
Event	International Conference on the Industrial Applications of the Mossbauer Effect - Madrid, Spain Duration: Oct 4 2004 → Oct 8 2004

Other

Other	International Conference on the Industrial Applications of the Mossbauer Effect
Country/Territory	Spain
City	Madrid
Period	10/4/04 → 10/8/04

ASJC Scopus subject areas

Physics and Astronomy(all)

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10.1063/1.1923669

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The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe2O4 . / Al-Rawas, A. D.; Widatallah, H. M.; Al-Omari, I. A.; Johnson, C.; Elzain, M. E.; Gismelseed, A. M.; Al-Taie, S.; Yousif, A. A.

AIP Conference Proceedings. Vol. 765 2005. p. 277-281.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Al-Rawas, AD , Widatallah, HM , Al-Omari, IA, Johnson, C, Elzain, ME , Gismelseed, AM, Al-Taie, S & Yousif, AA 2005, The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe2O4 . in AIP Conference Proceedings. vol. 765, pp. 277-281, International Conference on the Industrial Applications of the Mossbauer Effect, Madrid, Spain, 10/4/04. https://doi.org/10.1063/1.1923669

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title = "The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe2O4 ",

abstract = "The influence of mechanical milling and subsequent calcination of a 1:1 molar mixture of CuO and α-Fe2O3 on the formation of CuFe2O4 has been investigated with X-ray powder diffraction (XRD) and M{\"o}ssbauer spectroscopy. Pre-milling the mixture for 160h leads to the formation of CuFe2O4 nanocrystallites at 750°C. This temperature is ca. 400-450°C lower than the temperatures at which the material is conventionally prepared using the ceramic technique that involves no pre-milling of the reactants. Rietveld refinement of the XRD reveals the presence of both cubic and tetragonal crystal structures in the CuFe 2O4 obtained.",

author = "Al-Rawas, {A. D.} and Widatallah, {H. M.} and Al-Omari, {I. A.} and C. Johnson and Elzain, {M. E.} and Gismelseed, {A. M.} and S. Al-Taie and Yousif, {A. A.}",

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AU - Al-Rawas, A. D.

AU - Widatallah, H. M.

AU - Al-Omari, I. A.

AU - Johnson, C.

AU - Elzain, M. E.

AU - Gismelseed, A. M.

AU - Al-Taie, S.

AU - Yousif, A. A.

PY - 2005/4/26

Y1 - 2005/4/26

N2 - The influence of mechanical milling and subsequent calcination of a 1:1 molar mixture of CuO and α-Fe2O3 on the formation of CuFe2O4 has been investigated with X-ray powder diffraction (XRD) and Mössbauer spectroscopy. Pre-milling the mixture for 160h leads to the formation of CuFe2O4 nanocrystallites at 750°C. This temperature is ca. 400-450°C lower than the temperatures at which the material is conventionally prepared using the ceramic technique that involves no pre-milling of the reactants. Rietveld refinement of the XRD reveals the presence of both cubic and tetragonal crystal structures in the CuFe 2O4 obtained.

AB - The influence of mechanical milling and subsequent calcination of a 1:1 molar mixture of CuO and α-Fe2O3 on the formation of CuFe2O4 has been investigated with X-ray powder diffraction (XRD) and Mössbauer spectroscopy. Pre-milling the mixture for 160h leads to the formation of CuFe2O4 nanocrystallites at 750°C. This temperature is ca. 400-450°C lower than the temperatures at which the material is conventionally prepared using the ceramic technique that involves no pre-milling of the reactants. Rietveld refinement of the XRD reveals the presence of both cubic and tetragonal crystal structures in the CuFe 2O4 obtained.

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VL - 765

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BT - AIP Conference Proceedings

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Y2 - 4 October 2004 through 8 October 2004

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The influence of mechanical milling and subsequent calcination on the formation of nanocrystalline CuFe2O4

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