The effect of the rate of precursor production on the purity and aggregation morphology of nanoparticulate zinc oxide

Gráinne M. Duffy, Suresh C. Pillai, Declan E. McCormack*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

The synthesis of zinc oxide through the decomposition of a solid oxalate precursor was investigated. It was found that the rate of preparation of the precursor had a quantitative effect on the morphology and extent of surface ligation of particles produced; contrary to our expectations, it was found that the slow combination of reagents led to a less pure product. It has been determined that this time dependence mimics the variation of reactant ratios. Zinc oxide particles were produced from a number of reactant ratios, and were characterised by TEM, XRD, FT-IR and DSC. It was found that the size of the crystallites produced was not affected, but that the nature of their surface ligation did rely upon these parameters.

Original languageEnglish
Pages (from-to)181-184
Number of pages4
JournalJournal of Materials Chemistry
Volume17
Issue number2
DOIs
Publication statusPublished - 2007
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry

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