The dispersion of chemically active solutes in parallel flow

Anton Purnama*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

The irreversible loss of chemically active solutes by reactions at the boundary and the reversible adsorption on the flow boundary have been observed experimentally. Removal of solutes at the boundary alone reduces the rate of longitudinal shear dispersion; in contrast, the retention of solutes in the region close to the flow boundary alone increases the rate of longitudinal shear dispersion. Here an extension is given of the method of moments for chemically active solute dispersion to encompass this class of complications. Expressions are derived for the longitudinal shear dispersion coefficient and skewness. The results are applied to the practical example of a chemical flow reactor to quantify the effect of flow boundary retention when there exists reaction at the pipe wall.

Original languageEnglish
Pages (from-to)263-277
Number of pages15
JournalJournal of Fluid Mechanics
Volume290
DOIs
Publication statusPublished - May 1995
Externally publishedYes

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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