Synthesis of linked metal acetylide complexes for nonlinear optics

Simon J. Davies, Brian F G Johnson, Jack Lewis, Muhammad S. Khan

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Abstract

Treatment of [Mn(CO)5Br] (1) with a slight excess of Me3SnCCPh affords the known species [(CO)5Mn(CCPh)] (2), whereas reaction between 1 and Me3SnCCRCCSnMe3 (R = p-C6H4C6H4) gives the bimetallic complex [(CO)5MnCCRCCSnMe3] (3). This latter species is a good precursor for other syntheses, and treatment of 3 with a further equivalent of 1 gives [(CO)5MnCCRCCMn(CO)5] (4), while 3 with trans-[Pd(PBu3)2Cl2] affords [(CO)5MnCCRCCPd(PBu3)2Cl] (5).

Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume401
Issue number3
DOIs
Publication statusPublished - Jan 15 1991

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Nonlinear optics
Coordination Complexes
nonlinear optics
Metal complexes
synthesis
metals

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Synthesis of linked metal acetylide complexes for nonlinear optics. / Davies, Simon J.; Johnson, Brian F G; Lewis, Jack; Khan, Muhammad S.

In: Journal of Organometallic Chemistry, Vol. 401, No. 3, 15.01.1991.

Research output: Contribution to journalArticle

Davies, Simon J. ; Johnson, Brian F G ; Lewis, Jack ; Khan, Muhammad S. / Synthesis of linked metal acetylide complexes for nonlinear optics. In: Journal of Organometallic Chemistry. 1991 ; Vol. 401, No. 3.
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AB - Treatment of [Mn(CO)5Br] (1) with a slight excess of Me3SnCCPh affords the known species [(CO)5Mn(CCPh)] (2), whereas reaction between 1 and Me3SnCCRCCSnMe3 (R = p-C6H4C6H4) gives the bimetallic complex [(CO)5MnCCRCCSnMe3] (3). This latter species is a good precursor for other syntheses, and treatment of 3 with a further equivalent of 1 gives [(CO)5MnCCRCCMn(CO)5] (4), while 3 with trans-[Pd(PBu3)2Cl2] affords [(CO)5MnCCRCCPd(PBu3)2Cl] (5).

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