Synthesis of linked metal acetylide complexes for nonlinear optics

Simon J. Davies; Brian F.G. Johnson; Jack Lewis; Muhammad S. Khan

doi:10.1016/0022-328X(91)86238-L

Synthesis of linked metal acetylide complexes for nonlinear optics

Simon J. Davies^*, Brian F.G. Johnson, Jack Lewis, Muhammad S. Khan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

Treatment of [Mn(CO)₅Br] (1) with a slight excess of Me₃SnCCPh affords the known species [(CO)₅Mn(CCPh)] (2), whereas reaction between 1 and Me₃SnCCRCCSnMe₃ (R = p-C₆H₄C₆H₄) gives the bimetallic complex [(CO)₅MnCCRCCSnMe₃] (3). This latter species is a good precursor for other syntheses, and treatment of 3 with a further equivalent of 1 gives [(CO)₅MnCCRCCMn(CO)₅] (4), while 3 with trans-[Pd(PBu₃)₂Cl₂] affords [(CO)₅MnCCRCCPd(PBu₃)₂Cl] (5).

Original language	English
Pages (from-to)	C43-C45
Journal	Journal of Organometallic Chemistry
Volume	401
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(91)86238-L
Publication status	Published - Jan 15 1991
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Synthesis of linked metal acetylide complexes for nonlinear optics",

abstract = "Treatment of [Mn(CO)5Br] (1) with a slight excess of Me3SnCCPh affords the known species [(CO)5Mn(CCPh)] (2), whereas reaction between 1 and Me3SnCCRCCSnMe3 (R = p-C6H4C6H4) gives the bimetallic complex [(CO)5MnCCRCCSnMe3] (3). This latter species is a good precursor for other syntheses, and treatment of 3 with a further equivalent of 1 gives [(CO)5MnCCRCCMn(CO)5] (4), while 3 with trans-[Pd(PBu3)2Cl2] affords [(CO)5MnCCRCCPd(PBu3)2Cl] (5).",

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T1 - Synthesis of linked metal acetylide complexes for nonlinear optics

AU - Davies, Simon J.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Khan, Muhammad S.

PY - 1991/1/15

Y1 - 1991/1/15

N2 - Treatment of [Mn(CO)5Br] (1) with a slight excess of Me3SnCCPh affords the known species [(CO)5Mn(CCPh)] (2), whereas reaction between 1 and Me3SnCCRCCSnMe3 (R = p-C6H4C6H4) gives the bimetallic complex [(CO)5MnCCRCCSnMe3] (3). This latter species is a good precursor for other syntheses, and treatment of 3 with a further equivalent of 1 gives [(CO)5MnCCRCCMn(CO)5] (4), while 3 with trans-[Pd(PBu3)2Cl2] affords [(CO)5MnCCRCCPd(PBu3)2Cl] (5).

AB - Treatment of [Mn(CO)5Br] (1) with a slight excess of Me3SnCCPh affords the known species [(CO)5Mn(CCPh)] (2), whereas reaction between 1 and Me3SnCCRCCSnMe3 (R = p-C6H4C6H4) gives the bimetallic complex [(CO)5MnCCRCCSnMe3] (3). This latter species is a good precursor for other syntheses, and treatment of 3 with a further equivalent of 1 gives [(CO)5MnCCRCCMn(CO)5] (4), while 3 with trans-[Pd(PBu3)2Cl2] affords [(CO)5MnCCRCCPd(PBu3)2Cl] (5).

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Synthesis of linked metal acetylide complexes for nonlinear optics

Abstract

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