Synthesis and structural characterization of cobalt complexes derived from conjugated tetraynes

Jack Lewis, Bing Lin, Muhammad S. Khan, Muna R A Al-Mandhary, Paul R. Raithby

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Some novel tetrayne complexes RC2[Co2(CO)4dppm]CCCCC2[Co2(CO)4dppm]R (5) (where R = SiMe3, a; 4-MeC6H4, b; C6H5, c; 4-MeOC6H4, d; 4-FC6H4, e; dppm = 1,2-bis(diphenylphosphino)methane) have been synthesized either by oxidative coupling of RC2[Co2(CO)4dppm]CCH (4) or by lithiation and subsequent hydrolysis of RC2[Co2(CO)4dppm]CH CHCl (8). An X-ray structure determination of 5a reveals that the two Co2(CO)4dppm units are trans to each other. The cobalt units can be removed from 5 by oxidizing reagents.

Original languageEnglish
Pages (from-to)161-167
Number of pages7
JournalJournal of Organometallic Chemistry
Volume484
Issue number1-2
DOIs
Publication statusPublished - Dec 27 1994

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Keywords

  • Alkyne
  • Carbonyl
  • Cobalt
  • Crystal structure
  • Tetraynes

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

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