Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag2L2][BF4]2(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene)

Edwin C. Constable; Muhammad S. Khan; Michael C. Liptrot; Jack Lewis; Paul R. Raithby

doi:10.1016/S0020-1693(00)85883-1

Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene)

Edwin C. Constable^*, Muhammad S. Khan, Michael C. Liptrot, Jack Lewis, Paul R. Raithby

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Silver(I) ions do not act as templates for the formation of planar macrocyclic ligands based upon 2,2′-bipyridine or 1,10-phenanthroline, but incorporation of silver(I) into the performed macrocycles, obtained from transient template reactions, is facile. The complexes so obtained have a 1:1 ratio of silver to macrocycle. The crystal structure of the complex [Ag₂L₂][BF₄]₂ reveals a dimeric structure in the solid state with two distinct silver environments. Crystallographic data: space group P2₁/n, a=18.295(3), b=9.763(2), c=25.643(5) Å, β=105.03(1), V=4665 Å³, Z=4.

Original language	English
Pages (from-to)	239-244
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	179
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(00)85883-1
Publication status	Published - Jan 15 1991
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(00)85883-1

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Constable, E. C., Khan, M. S., Liptrot, M. C., Lewis, J., & Raithby, P. R. (1991). Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene). Inorganica Chimica Acta, 179(2), 239-244. https://doi.org/10.1016/S0020-1693(00)85883-1

Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene). / Constable, Edwin C.; Khan, Muhammad S.; Liptrot, Michael C. et al.
In: Inorganica Chimica Acta, Vol. 179, No. 2, 15.01.1991, p. 239-244.

Research output: Contribution to journal › Article › peer-review

Constable, EC, Khan, MS, Liptrot, MC, Lewis, J & Raithby, PR 1991, 'Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene)', Inorganica Chimica Acta, vol. 179, no. 2, pp. 239-244. https://doi.org/10.1016/S0020-1693(00)85883-1

Constable EC, Khan MS, Liptrot MC, Lewis J, Raithby PR. Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene). Inorganica Chimica Acta. 1991 Jan 15;179(2):239-244. doi: 10.1016/S0020-1693(00)85883-1

Constable, Edwin C. ; Khan, Muhammad S. ; Liptrot, Michael C. et al. / Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene). In: Inorganica Chimica Acta. 1991 ; Vol. 179, No. 2. pp. 239-244.

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title = "Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag2L2][BF4]2(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene)",

abstract = "Silver(I) ions do not act as templates for the formation of planar macrocyclic ligands based upon 2,2′-bipyridine or 1,10-phenanthroline, but incorporation of silver(I) into the performed macrocycles, obtained from transient template reactions, is facile. The complexes so obtained have a 1:1 ratio of silver to macrocycle. The crystal structure of the complex [Ag2L2][BF4]2 reveals a dimeric structure in the solid state with two distinct silver environments. Crystallographic data: space group P21/n, a=18.295(3), b=9.763(2), c=25.643(5) {\AA}, β=105.03(1), V=4665 {\AA}3, Z=4.",

author = "Constable, {Edwin C.} and Khan, {Muhammad S.} and Liptrot, {Michael C.} and Jack Lewis and Raithby, {Paul R.}",

note = "Funding Information: We thank the SERC for the award of a studentship (M.C.L.), the Royal Society and the Nuffield Foundation for a Fellowship (M.S.K.) and Dhaka University, Bangladesh for study leave (M.S.K.).",

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AU - Constable, Edwin C.

AU - Khan, Muhammad S.

AU - Liptrot, Michael C.

AU - Lewis, Jack

AU - Raithby, Paul R.

N1 - Funding Information: We thank the SERC for the award of a studentship (M.C.L.), the Royal Society and the Nuffield Foundation for a Fellowship (M.S.K.) and Dhaka University, Bangladesh for study leave (M.S.K.).

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