Abstract
We investigate the effect of backflow on the translocation dynamics of short, flexible polymer chains threading through a small hole in a wall. We find that hydrodynamic interactions between polymer beads play an important role in determining the translocation time distribution: as a monomer moves through the hole it sets up a flow field which transfers momentum to neighboring monomers, thus helping them to move in the same direction. Translocation times are calculated by using the velocity-Verlet algorithm to solve the equations of motion of a polymer which moves in a fluid described by the stochastic rotation algorithm, a particle-based Navier-Stokes solver.
Original language | English |
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Article number | 234903 |
Journal | Journal of Chemical Physics |
Volume | 123 |
Issue number | 23 |
DOIs | |
Publication status | Published - 2005 |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry