New application of Burgess reagent in its reaction with epoxides

Uwe Rinner; David R. Adams; Maria L. Dos Santos; Khalil A. Abboud; Tomas Hudlicky

doi:10.1055/s-2003-40356

New application of Burgess reagent in its reaction with epoxides

Uwe Rinner, David R. Adams, Maria L. Dos Santos, Khalil A. Abboud, Tomas Hudlicky^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Burgess reagent, (methoxycarbonylsulfamoyl)triethylammonium hydroxide, usually used for the dehydration of secondary or tertiary alcohols, was successfully employed in the formation of sulfamidates from the corresponding epoxides. It was further shown that the same reaction with aromatic epoxides results in the formation of seven-membered ring systems.

Original language	English
Pages (from-to)	1247-1252
Number of pages	6
Journal	Synlett
Issue number	9 SPEC. ISS.
DOIs	https://doi.org/10.1055/s-2003-40356
Publication status	Published - 2003
Externally published	Yes

Keywords

Amino alcohols
Burgess reagent
Epoxides
Heterocycles
Regioselectivity

ASJC Scopus subject areas

Organic Chemistry

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title = "New application of Burgess reagent in its reaction with epoxides",

abstract = "Burgess reagent, (methoxycarbonylsulfamoyl)triethylammonium hydroxide, usually used for the dehydration of secondary or tertiary alcohols, was successfully employed in the formation of sulfamidates from the corresponding epoxides. It was further shown that the same reaction with aromatic epoxides results in the formation of seven-membered ring systems.",

keywords = "Amino alcohols, Burgess reagent, Epoxides, Heterocycles, Regioselectivity",

author = "Uwe Rinner and Adams, {David R.} and {Dos Santos}, {Maria L.} and Abboud, {Khalil A.} and Tomas Hudlicky",

year = "2003",

doi = "10.1055/s-2003-40356",

language = "English",

pages = "1247--1252",

journal = "Synlett",

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T1 - New application of Burgess reagent in its reaction with epoxides

AU - Rinner, Uwe

AU - Adams, David R.

AU - Dos Santos, Maria L.

AU - Abboud, Khalil A.

AU - Hudlicky, Tomas

PY - 2003

Y1 - 2003

N2 - Burgess reagent, (methoxycarbonylsulfamoyl)triethylammonium hydroxide, usually used for the dehydration of secondary or tertiary alcohols, was successfully employed in the formation of sulfamidates from the corresponding epoxides. It was further shown that the same reaction with aromatic epoxides results in the formation of seven-membered ring systems.

AB - Burgess reagent, (methoxycarbonylsulfamoyl)triethylammonium hydroxide, usually used for the dehydration of secondary or tertiary alcohols, was successfully employed in the formation of sulfamidates from the corresponding epoxides. It was further shown that the same reaction with aromatic epoxides results in the formation of seven-membered ring systems.

KW - Amino alcohols

KW - Burgess reagent

KW - Epoxides

KW - Heterocycles

KW - Regioselectivity

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U2 - 10.1055/s-2003-40356

DO - 10.1055/s-2003-40356

M3 - Article

AN - SCOPUS:0038103857

SN - 0936-5214

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JO - Synlett

JF - Synlett

IS - 9 SPEC. ISS.

ER -

New application of Burgess reagent in its reaction with epoxides

Abstract

Keywords

ASJC Scopus subject areas

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