New application of Burgess reagent in its reaction with epoxides

Uwe Rinner, David R. Adams, Maria L. Dos Santos, Khalil A. Abboud, Tomas Hudlicky

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Burgess reagent, (methoxycarbonylsulfamoyl)triethylammonium hydroxide, usually used for the dehydration of secondary or tertiary alcohols, was successfully employed in the formation of sulfamidates from the corresponding epoxides. It was further shown that the same reaction with aromatic epoxides results in the formation of seven-membered ring systems.

Original languageEnglish
Pages (from-to)1247-1252
Number of pages6
JournalSynlett
Issue number9 SPEC. ISS.
Publication statusPublished - 2003

Keywords

  • Amino alcohols
  • Burgess reagent
  • Epoxides
  • Heterocycles
  • Regioselectivity

ASJC Scopus subject areas

  • Organic Chemistry

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  • Cite this

    Rinner, U., Adams, D. R., Dos Santos, M. L., Abboud, K. A., & Hudlicky, T. (2003). New application of Burgess reagent in its reaction with epoxides. Synlett, (9 SPEC. ISS.), 1247-1252.