Abstract
Understanding the structural and thermomechanical properties of mixed-phase polymeric materials and composites at the nanoscale is one of the key challenges in developing a new class of materials with improved structural properties. Here, we present a nondestructive method, local thermal analysis (LTA), based on a heated atomic force microscope cantilever, for the nanoscale characterization of structural and thermal properties of polymer composites. The technique allows measurement of the local melting point, the dehydratation temperature, and the thermal expansion. Moreover, by monitoring the indentation with the heated tip after the melting point, the LTA may be used for phase assignment in multilayered polymers. The measured melting temperatures are found to be reproducible and match satisfactorily with those obtained by differential scanning calorimetry. Finally, the LTA technique coupled with transmission electron microscopy allows us to obtain a more precise description of the nanostructure of a recently developed cellulose/PEO nanocomposite.
| Original language | English |
|---|---|
| Pages (from-to) | 8849-8856 |
| Number of pages | 8 |
| Journal | Journal of Physical Chemistry C |
| Volume | 116 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - Apr 19 2012 |
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ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Energy(all)
- Surfaces, Coatings and Films
- Physical and Theoretical Chemistry
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Nanoscale thermal analysis of multiphase polymer nanocomposites. / Souier, Tewfik; Samad, Yarjan Abdul; Lalia, Boor Singh; Hashaikeh, Raed; Chiesa, Matteo.
In: Journal of Physical Chemistry C, Vol. 116, No. 15, 19.04.2012, p. 8849-8856.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nanoscale thermal analysis of multiphase polymer nanocomposites
AU - Souier, Tewfik
AU - Samad, Yarjan Abdul
AU - Lalia, Boor Singh
AU - Hashaikeh, Raed
AU - Chiesa, Matteo
PY - 2012/4/19
Y1 - 2012/4/19
N2 - Understanding the structural and thermomechanical properties of mixed-phase polymeric materials and composites at the nanoscale is one of the key challenges in developing a new class of materials with improved structural properties. Here, we present a nondestructive method, local thermal analysis (LTA), based on a heated atomic force microscope cantilever, for the nanoscale characterization of structural and thermal properties of polymer composites. The technique allows measurement of the local melting point, the dehydratation temperature, and the thermal expansion. Moreover, by monitoring the indentation with the heated tip after the melting point, the LTA may be used for phase assignment in multilayered polymers. The measured melting temperatures are found to be reproducible and match satisfactorily with those obtained by differential scanning calorimetry. Finally, the LTA technique coupled with transmission electron microscopy allows us to obtain a more precise description of the nanostructure of a recently developed cellulose/PEO nanocomposite.
AB - Understanding the structural and thermomechanical properties of mixed-phase polymeric materials and composites at the nanoscale is one of the key challenges in developing a new class of materials with improved structural properties. Here, we present a nondestructive method, local thermal analysis (LTA), based on a heated atomic force microscope cantilever, for the nanoscale characterization of structural and thermal properties of polymer composites. The technique allows measurement of the local melting point, the dehydratation temperature, and the thermal expansion. Moreover, by monitoring the indentation with the heated tip after the melting point, the LTA may be used for phase assignment in multilayered polymers. The measured melting temperatures are found to be reproducible and match satisfactorily with those obtained by differential scanning calorimetry. Finally, the LTA technique coupled with transmission electron microscopy allows us to obtain a more precise description of the nanostructure of a recently developed cellulose/PEO nanocomposite.
UR - http://www.scopus.com/inward/record.url?scp=84860147610&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84860147610&partnerID=8YFLogxK
U2 - 10.1021/jp301410e
DO - 10.1021/jp301410e
M3 - Article
AN - SCOPUS:84860147610
VL - 116
SP - 8849
EP - 8856
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 15
ER -