General synthesis of highly functionalized cyclopentane segments for the preparation of jatrophane diterpenes

Christoph Lentsch, Uwe Rinner

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

Short and efficient syntheses of two diastereomeric cyclopentane segments present in most jatrophane diterpenes were achieved. Key steps are a stereoselective C-2 elongation, an RCM, and a hydroboration reaction. An orthogonal protecting group methodology makes these segments useful building blocks for diterpene synthesis.

Original languageEnglish
Pages (from-to)5326-5328
Number of pages3
JournalOrganic Letters
Volume11
Issue number22
DOIs
Publication statusPublished - 2009

Fingerprint

Cyclopentanes
Diterpenes
hydroboration
preparation
synthesis
elongation
Elongation
methodology
jatrophane

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

General synthesis of highly functionalized cyclopentane segments for the preparation of jatrophane diterpenes. / Lentsch, Christoph; Rinner, Uwe.

In: Organic Letters, Vol. 11, No. 22, 2009, p. 5326-5328.

Research output: Contribution to journalArticle

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