General synthesis of highly functionalized cyclopentane segments for the preparation of jatrophane diterpenes

Christoph Lentsch, Uwe Rinner

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29 Citations (Scopus)

Abstract

Short and efficient syntheses of two diastereomeric cyclopentane segments present in most jatrophane diterpenes were achieved. Key steps are a stereoselective C-2 elongation, an RCM, and a hydroboration reaction. An orthogonal protecting group methodology makes these segments useful building blocks for diterpene synthesis.

Original languageEnglish
Pages (from-to)5326-5328
Number of pages3
JournalOrganic Letters
Volume11
Issue number22
DOIs
Publication statusPublished - 2009

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ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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