Electronic structure of platinum-containing polyynes

O. Lhost, J. M. Toussaint, J. L. Bredas, H. F. Wittmann, K. Fuhrmann, R. H. Friend, M. S. Khan, J. Lewis

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Using an Extended Hückel approach, we investigate the electronic structure of a class of metal-containing polyynes (oligomers and polymers). These systems contain square-planar coordinated platinum sites linked by conjugated sequences of acetylenic units. We mainly focus on the evolution of the first optical transition as a function of the molecule size when going from short oligomers to the polymer. Our primary interest is in establishing the contribution of the metal atoms in the conjugation path.

Original languageEnglish
Pages (from-to)4525-4530
Number of pages6
JournalSynthetic Metals
Volume57
Issue number2-3
DOIs
Publication statusPublished - Apr 19 1993

Fingerprint

Polyacetylenes
Platinum
oligomers
Oligomers
Electronic structure
Polymers
platinum
Metals
electronic structure
Optical transitions
polymers
conjugation
optical transition
metals
Atoms
Molecules
atoms
molecules

Keywords

  • conjugated polymer
  • extended Hückel.
  • polyynes
  • transition-metal complex

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Lhost, O., Toussaint, J. M., Bredas, J. L., Wittmann, H. F., Fuhrmann, K., Friend, R. H., ... Lewis, J. (1993). Electronic structure of platinum-containing polyynes. Synthetic Metals, 57(2-3), 4525-4530. https://doi.org/10.1016/0379-6779(93)90777-T

Electronic structure of platinum-containing polyynes. / Lhost, O.; Toussaint, J. M.; Bredas, J. L.; Wittmann, H. F.; Fuhrmann, K.; Friend, R. H.; Khan, M. S.; Lewis, J.

In: Synthetic Metals, Vol. 57, No. 2-3, 19.04.1993, p. 4525-4530.

Research output: Contribution to journalArticle

Lhost, O, Toussaint, JM, Bredas, JL, Wittmann, HF, Fuhrmann, K, Friend, RH, Khan, MS & Lewis, J 1993, 'Electronic structure of platinum-containing polyynes', Synthetic Metals, vol. 57, no. 2-3, pp. 4525-4530. https://doi.org/10.1016/0379-6779(93)90777-T
Lhost O, Toussaint JM, Bredas JL, Wittmann HF, Fuhrmann K, Friend RH et al. Electronic structure of platinum-containing polyynes. Synthetic Metals. 1993 Apr 19;57(2-3):4525-4530. https://doi.org/10.1016/0379-6779(93)90777-T
Lhost, O. ; Toussaint, J. M. ; Bredas, J. L. ; Wittmann, H. F. ; Fuhrmann, K. ; Friend, R. H. ; Khan, M. S. ; Lewis, J. / Electronic structure of platinum-containing polyynes. In: Synthetic Metals. 1993 ; Vol. 57, No. 2-3. pp. 4525-4530.
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