Concentration fluctuations and thermodynamic properties of demixing liquid binary alloys

R. N. Singh, S. K. Yu, F. Sommer

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

An optimized set of thermodynamic functions of liquid CdGa and BiGa alloys is obtained by a least-squares method through optimization of different available experimental data such as phase diagram and thermodynamic properties. These results can be described using a simple model, where the existence of polyatomic self-associates has been considered. The temperature and concentration fluctuations in the long wavelength limit, which are most sensitive to small changes in both temperature and concentration above the miscibility gap, can be described assuming a temperature dependence of the number of self-associated atoms and of the interchange energy.

Original languageEnglish
Pages (from-to)407-411
Number of pages5
JournalJournal of Non-Crystalline Solids
Volume156-158
Issue numberPART 1
DOIs
Publication statusPublished - May 2 1993

Fingerprint

liquid alloys
Binary alloys
binary alloys
Thermodynamic properties
thermodynamic properties
miscibility gap
Liquids
least squares method
phase diagrams
Interchanges
Temperature
thermodynamics
temperature dependence
optimization
Phase diagrams
temperature
liquids
Solubility
wavelengths
Thermodynamics

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

Cite this

Concentration fluctuations and thermodynamic properties of demixing liquid binary alloys. / Singh, R. N.; Yu, S. K.; Sommer, F.

In: Journal of Non-Crystalline Solids, Vol. 156-158, No. PART 1, 02.05.1993, p. 407-411.

Research output: Contribution to journalArticle

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