Bulk and surface properties of liquid In-Cu alloys

O. Akinlade, R. N. Singh

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

In-Cu is a weak interacting system (the excess free energy of mixing GM xs≈-0.2RT at equiatomic composition) but the composition dependence of the thermodynamic properties exhibit interesting features. GM xs is negative in the Cu-rich region and positive for the In-rich end. Similarly other thermodynamic properties are asymmetric about the equiatomic composition. Such an interesting feature is explained here on the basis that a complex of the form Cu4In exists in the bulk phase. Its energetics are used to study the surface composition of the In-Cu liquid alloys. Our study indicates that the surface is enormously rich with indium concentrations throughout the composition of the alloys.

Original languageEnglish
Pages (from-to)84-90
Number of pages7
JournalJournal of Alloys and Compounds
Volume333
Issue number1-2
DOIs
Publication statusPublished - Feb 14 2002

Fingerprint

Surface properties
Liquids
Chemical analysis
Thermodynamic properties
Indium
Surface structure
Free energy

Keywords

  • Enthalpy
  • Entropy
  • Liquid alloys
  • Thermodynamic modelling

ASJC Scopus subject areas

  • Metals and Alloys

Cite this

Bulk and surface properties of liquid In-Cu alloys. / Akinlade, O.; Singh, R. N.

In: Journal of Alloys and Compounds, Vol. 333, No. 1-2, 14.02.2002, p. 84-90.

Research output: Contribution to journalArticle

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