Abstract
In this paper, Shuwaymiyah palygorskite in the Sultanate of Oman has been characterized mineralogically by X-ray diffraction (XRD) and electron microscopy, chemically by oxide compositions, structural formulae, and cation exchange capacity (CEC), and physically by specific surface area and adsorption isotherms. Batch adsorption studies were performed to evaluate the adsorption performance of methylene blue (MB) basic dye on the local clay mineral. The quantitative XRD analysis indicates that the purity of some selected samples of palygorskite clay is very high (about 70% of the clay minerals are palygorskite and 30% kaolinite). The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images clearly support this conclusion. The adsorption equilibrium revealed that Shuwaymiyah palygorskite clay can uptake up to 51 mg of MB per 1 g mass of clay. MB adsorption is best fitted by Langmuir isotherm, and a pseudo-second-order kinetic model can be efficiently used to predict the kinetic of adsorption of MB by the palygorskite. The results obtained from these laboratory-scale adsorption tests indicate the promising adsorption capability of the Omani palygorskite.
| Original language | English |
|---|---|
| Pages (from-to) | 1317-1327 |
| Number of pages | 11 |
| Journal | Environmental Geology |
| Volume | 51 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Feb 2007 |
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Keywords
- Adsorption
- Methylene blue
- Palygorskite
- Physio-chemical characterization
ASJC Scopus subject areas
- Earth and Planetary Sciences (miscellaneous)
- Environmental Science(all)
- Environmental Chemistry
- Water Science and Technology
Cite this
Adsorption capacity and mineralogical and physico-chemical characteristics of Shuwaymiyah palygorskite (Oman). / Al-Futaisi, Ahmed; Jamrah, Ahmad; Al-Rawas, Amer; Al-Hanai, Saif.
In: Environmental Geology, Vol. 51, No. 8, 02.2007, p. 1317-1327.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Adsorption capacity and mineralogical and physico-chemical characteristics of Shuwaymiyah palygorskite (Oman)
AU - Al-Futaisi, Ahmed
AU - Jamrah, Ahmad
AU - Al-Rawas, Amer
AU - Al-Hanai, Saif
PY - 2007/2
Y1 - 2007/2
N2 - In this paper, Shuwaymiyah palygorskite in the Sultanate of Oman has been characterized mineralogically by X-ray diffraction (XRD) and electron microscopy, chemically by oxide compositions, structural formulae, and cation exchange capacity (CEC), and physically by specific surface area and adsorption isotherms. Batch adsorption studies were performed to evaluate the adsorption performance of methylene blue (MB) basic dye on the local clay mineral. The quantitative XRD analysis indicates that the purity of some selected samples of palygorskite clay is very high (about 70% of the clay minerals are palygorskite and 30% kaolinite). The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images clearly support this conclusion. The adsorption equilibrium revealed that Shuwaymiyah palygorskite clay can uptake up to 51 mg of MB per 1 g mass of clay. MB adsorption is best fitted by Langmuir isotherm, and a pseudo-second-order kinetic model can be efficiently used to predict the kinetic of adsorption of MB by the palygorskite. The results obtained from these laboratory-scale adsorption tests indicate the promising adsorption capability of the Omani palygorskite.
AB - In this paper, Shuwaymiyah palygorskite in the Sultanate of Oman has been characterized mineralogically by X-ray diffraction (XRD) and electron microscopy, chemically by oxide compositions, structural formulae, and cation exchange capacity (CEC), and physically by specific surface area and adsorption isotherms. Batch adsorption studies were performed to evaluate the adsorption performance of methylene blue (MB) basic dye on the local clay mineral. The quantitative XRD analysis indicates that the purity of some selected samples of palygorskite clay is very high (about 70% of the clay minerals are palygorskite and 30% kaolinite). The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images clearly support this conclusion. The adsorption equilibrium revealed that Shuwaymiyah palygorskite clay can uptake up to 51 mg of MB per 1 g mass of clay. MB adsorption is best fitted by Langmuir isotherm, and a pseudo-second-order kinetic model can be efficiently used to predict the kinetic of adsorption of MB by the palygorskite. The results obtained from these laboratory-scale adsorption tests indicate the promising adsorption capability of the Omani palygorskite.
KW - Adsorption
KW - Methylene blue
KW - Palygorskite
KW - Physio-chemical characterization
UR - http://www.scopus.com/inward/record.url?scp=33846941947&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33846941947&partnerID=8YFLogxK
U2 - 10.1007/s00254-006-0430-y
DO - 10.1007/s00254-006-0430-y
M3 - Article
VL - 51
SP - 1317
EP - 1327
JO - Environmental Earth Sciences
JF - Environmental Earth Sciences
SN - 1866-6280
IS - 8
ER -