Enantioselective homogenous catalysis: Transferring chirality via phosphine complexes. A 2-D NMR approach

Paul S. Pregosin; Massimiliano Valentini

Enantioselective homogenous catalysis: Transferring chirality via phosphine complexes. A 2-D NMR approach

Paul S. Pregosin^*, Massimiliano Valentini

^*المؤلف المقابل لهذا العمل

نتاج البحث: المساهمة في مجلة › Article › مراجعة النظراء

8 اقتباسات (Scopus)

ملخص

An NMR approach to understanding structure in chiral transition metal complexes is described. The ideas of ″intrusiveness″ and ″rigidity″ in connection with the transfer of chirality are explored. Data from 2-D NMR spectroscopy, and specifically NOESY measurements, are extrapolated to explain how 3,5-dialkyl substituents can enhance enantioselectivity in several reactions.

اللغة الأصلية	English
الصفحات (من إلى)	529-539
عدد الصفحات	11
دورية	Enantiomer
مستوى الصوت	4
رقم الإصدار	6
حالة النشر	Published - 1999
منشور خارجيًا	نعم

ASJC Scopus subject areas

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الملفات والروابط الأخرى

قم بذكر هذا

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title = "Enantioselective homogenous catalysis: Transferring chirality via phosphine complexes. A 2-D NMR approach",

abstract = "An NMR approach to understanding structure in chiral transition metal complexes is described. The ideas of ″intrusiveness″ and ″rigidity″ in connection with the transfer of chirality are explored. Data from 2-D NMR spectroscopy, and specifically NOESY measurements, are extrapolated to explain how 3,5-dialkyl substituents can enhance enantioselectivity in several reactions.",

keywords = "2-D NMR, Enantioselective homogenous catalysis, NOESY",

author = "Pregosin, {Paul S.} and Massimiliano Valentini",

year = "1999",

language = "English",

volume = "4",

pages = "529--539",

journal = "Enantiomer",

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TY - JOUR

T1 - Enantioselective homogenous catalysis

T2 - Transferring chirality via phosphine complexes. A 2-D NMR approach

AU - Pregosin, Paul S.

AU - Valentini, Massimiliano

PY - 1999

Y1 - 1999

N2 - An NMR approach to understanding structure in chiral transition metal complexes is described. The ideas of ″intrusiveness″ and ″rigidity″ in connection with the transfer of chirality are explored. Data from 2-D NMR spectroscopy, and specifically NOESY measurements, are extrapolated to explain how 3,5-dialkyl substituents can enhance enantioselectivity in several reactions.

AB - An NMR approach to understanding structure in chiral transition metal complexes is described. The ideas of ″intrusiveness″ and ″rigidity″ in connection with the transfer of chirality are explored. Data from 2-D NMR spectroscopy, and specifically NOESY measurements, are extrapolated to explain how 3,5-dialkyl substituents can enhance enantioselectivity in several reactions.

KW - 2-D NMR

KW - Enantioselective homogenous catalysis

KW - NOESY

UR - http://www.scopus.com/inward/record.url?scp=0033393880&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033393880&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0033393880

SN - 1024-2430

VL - 4

SP - 529

EP - 539

JO - Enantiomer

JF - Enantiomer

IS - 6

ER -

Enantioselective homogenous catalysis: Transferring chirality via phosphine complexes. A 2-D NMR approach

ملخص

ASJC Scopus subject areas

الملفات والروابط الأخرى

بصمة

قم بذكر هذا