ملخص
The complex formation model of Bhatia and Hargrove (BH) to explain the thermodynamic properties of compound forming A-B alloys is reformulated using a quasi-lattice picture. The formulation is explicitly carried out to an approximation where the pseudo-ternary alloy (of A and B atoms and AμBV complexes (μ, v small integers)), envisaged in BH, is treated in the quasichemical approximation. It is advantageous over BH in two major respects: Firstly, it gives useful insight into the two approximations used in BH, since these follow from it by simply going to a lower (zeroth) approximation and setting the coordination number z of the alloy to be z = 2 and z =∞. Secondly, unlike the BH approach, it provides also an expression for the short range order parameter α1, for nearest neighbours. The effect of varying z in the formulae is examined and a brief discussion of α1 is given.
اللغة الأصلية | English |
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الصفحات (من إلى) | 177-190 |
عدد الصفحات | 14 |
دورية | Physics and Chemistry of Liquids |
مستوى الصوت | 13 |
رقم الإصدار | 3 |
المعرِّفات الرقمية للأشياء | |
حالة النشر | Published - يناير 1 1984 |
منشور خارجيًا | نعم |
ASJC Scopus subject areas
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