Abstract
X-ray crystal structures are reported for six transition-metal complexes of the ligands 1,2-bis(8-quinolyloxymethyl)benzene (3) and 1,3-bis(8-quinolyloxymethyl)benzene (4). In three mononuclear copper(II) and cobalt(II) complexes, 3 acts as a chelating ligand with either N, O, N′-tridentate or N,O,O′,N′-tetradentate coordination. A novel dinuclear silver(I) complex of 3 is shown to be stabilised by a number of weak metal-ligand contacts and multiple intramolecular π-π stacking interactions. In two dinuclear copper(II) nitrate complexes of 4, the ligand adopts very different bridging modes of coordination.
Original language | English |
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Pages (from-to) | 329-334 |
Number of pages | 6 |
Journal | European Journal of Inorganic Chemistry |
Issue number | 2 |
Publication status | Published - Jan 23 2004 |
Keywords
- Bridging ligands
- Cobalt
- Copper
- N,O ligands
- Silver
ASJC Scopus subject areas
- Inorganic Chemistry