Visible photodegradation of ibuprofen and 2,4-D in simulated waste water using sustainable metal free-hybrids based on carbon nitride and biochar

Amit Kumar, Gaurav Sharma, Mu Naushad, Ala Al-Muhtaseb, Ajay Kumar, Indu Hira, Tansir Ahamad, Ayman A. Ghfar, Florian J. Stadler

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Rational designing of metal-free carbon nitride based photocatalysts can lead to an excellent optical response and a higher photocatalytic activity driven by visible and solar light. This combines green photocatalytic technology with greener materials prepared by facile approaches for environmental remediation. Herein we report utilization of star photocatalyst g-C3N4 (CN) to form highly efficient hetero-assemblies along with acidified g-C3N4 (ACN), polyaniline (PANI), reduced graphene oxide (RGO) and biochar. By use of these organic semiconductors we synthesize g-C3N4/ACN/RGO@Biochar (GARB), g-C3N4/PANI/RGO@Biochar (GPRB) and ACN/PANI/RGO@Biochar (APRB) nano-assemblies with different optical response and band edge positions for a better charge flow and reduced recombination of carriers. These synthesized catalysts were used for visible light powered degradation of 2,4-Dichlorophenoxy acetic acid (2,4-D) and ibuprofen (IBN). APRB performs the best and degrades 99.7% and 98.4% of 2,4-D and IBN (20 mg L−1) under Xe lamp exposure in 50 min and retention of high activity in natural sunlight. Optical analysis, photoelectrochemical response and radical quenching studies show both hydroxyl and superoxide radical anions as major reactive species and a Z-scheme photocatalytic mechanism. RGO acts as an electron mediator and protects higher positioned bands of PANI and ACN in APRB for a remarkable photocatalytic activity for a metal free material. The degradation pathway was analyzed by LC-MS analysis and 42% and 40% total organic carbon was removed in 2 h for 2,4-D and IBN degradation respectively. The toxicity of degraded products was analyzed by analyzing viability of human peripheral blood cells with retaining of 99.1% cells.

Original languageEnglish
Pages (from-to)1164-1175
Number of pages12
JournalJournal of Environmental Management
Volume231
DOIs
Publication statusPublished - Feb 1 2019

Fingerprint

Carbon nitride
2,4 dichlorophenoxyacetic acid
Photodegradation
photodegradation
Graphene
Polyaniline
Wastewater
oxide
Oxides
metal
carbon
Metals
Photocatalysts
Degradation
degradation
Environmental technology
Semiconducting organic compounds
response analysis
Organic carbon
Electric lamps

Keywords

  • Biochar: pharmaceutical effluents
  • Carbon nitride
  • Environmental detoxification
  • Nano-assemblies
  • Photocatalysis
  • Water treatment

ASJC Scopus subject areas

  • Environmental Engineering
  • Waste Management and Disposal
  • Management, Monitoring, Policy and Law

Cite this

Visible photodegradation of ibuprofen and 2,4-D in simulated waste water using sustainable metal free-hybrids based on carbon nitride and biochar. / Kumar, Amit; Sharma, Gaurav; Naushad, Mu; Al-Muhtaseb, Ala; Kumar, Ajay; Hira, Indu; Ahamad, Tansir; Ghfar, Ayman A.; Stadler, Florian J.

In: Journal of Environmental Management, Vol. 231, 01.02.2019, p. 1164-1175.

Research output: Contribution to journalArticle

Kumar, Amit ; Sharma, Gaurav ; Naushad, Mu ; Al-Muhtaseb, Ala ; Kumar, Ajay ; Hira, Indu ; Ahamad, Tansir ; Ghfar, Ayman A. ; Stadler, Florian J. / Visible photodegradation of ibuprofen and 2,4-D in simulated waste water using sustainable metal free-hybrids based on carbon nitride and biochar. In: Journal of Environmental Management. 2019 ; Vol. 231. pp. 1164-1175.
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AU - Kumar, Amit

AU - Sharma, Gaurav

AU - Naushad, Mu

AU - Al-Muhtaseb, Ala

AU - Kumar, Ajay

AU - Hira, Indu

AU - Ahamad, Tansir

AU - Ghfar, Ayman A.

AU - Stadler, Florian J.

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N2 - Rational designing of metal-free carbon nitride based photocatalysts can lead to an excellent optical response and a higher photocatalytic activity driven by visible and solar light. This combines green photocatalytic technology with greener materials prepared by facile approaches for environmental remediation. Herein we report utilization of star photocatalyst g-C3N4 (CN) to form highly efficient hetero-assemblies along with acidified g-C3N4 (ACN), polyaniline (PANI), reduced graphene oxide (RGO) and biochar. By use of these organic semiconductors we synthesize g-C3N4/ACN/RGO@Biochar (GARB), g-C3N4/PANI/RGO@Biochar (GPRB) and ACN/PANI/RGO@Biochar (APRB) nano-assemblies with different optical response and band edge positions for a better charge flow and reduced recombination of carriers. These synthesized catalysts were used for visible light powered degradation of 2,4-Dichlorophenoxy acetic acid (2,4-D) and ibuprofen (IBN). APRB performs the best and degrades 99.7% and 98.4% of 2,4-D and IBN (20 mg L−1) under Xe lamp exposure in 50 min and retention of high activity in natural sunlight. Optical analysis, photoelectrochemical response and radical quenching studies show both hydroxyl and superoxide radical anions as major reactive species and a Z-scheme photocatalytic mechanism. RGO acts as an electron mediator and protects higher positioned bands of PANI and ACN in APRB for a remarkable photocatalytic activity for a metal free material. The degradation pathway was analyzed by LC-MS analysis and 42% and 40% total organic carbon was removed in 2 h for 2,4-D and IBN degradation respectively. The toxicity of degraded products was analyzed by analyzing viability of human peripheral blood cells with retaining of 99.1% cells.

AB - Rational designing of metal-free carbon nitride based photocatalysts can lead to an excellent optical response and a higher photocatalytic activity driven by visible and solar light. This combines green photocatalytic technology with greener materials prepared by facile approaches for environmental remediation. Herein we report utilization of star photocatalyst g-C3N4 (CN) to form highly efficient hetero-assemblies along with acidified g-C3N4 (ACN), polyaniline (PANI), reduced graphene oxide (RGO) and biochar. By use of these organic semiconductors we synthesize g-C3N4/ACN/RGO@Biochar (GARB), g-C3N4/PANI/RGO@Biochar (GPRB) and ACN/PANI/RGO@Biochar (APRB) nano-assemblies with different optical response and band edge positions for a better charge flow and reduced recombination of carriers. These synthesized catalysts were used for visible light powered degradation of 2,4-Dichlorophenoxy acetic acid (2,4-D) and ibuprofen (IBN). APRB performs the best and degrades 99.7% and 98.4% of 2,4-D and IBN (20 mg L−1) under Xe lamp exposure in 50 min and retention of high activity in natural sunlight. Optical analysis, photoelectrochemical response and radical quenching studies show both hydroxyl and superoxide radical anions as major reactive species and a Z-scheme photocatalytic mechanism. RGO acts as an electron mediator and protects higher positioned bands of PANI and ACN in APRB for a remarkable photocatalytic activity for a metal free material. The degradation pathway was analyzed by LC-MS analysis and 42% and 40% total organic carbon was removed in 2 h for 2,4-D and IBN degradation respectively. The toxicity of degraded products was analyzed by analyzing viability of human peripheral blood cells with retaining of 99.1% cells.

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KW - Carbon nitride

KW - Environmental detoxification

KW - Nano-assemblies

KW - Photocatalysis

KW - Water treatment

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