Abstract
A first principle theoretical scheme which is based on pseudopotential perturbation theory, the thermodynamics of hard sphere systems and the variational method based on Gibbs-Bogoliaubov inequality is used to investigate the specific heat of liquid Rb in the undercooled region (T< Tm). Cl p is found to increase with decreasing T and exhibits a maxima in the vicinity of 60 K. The anomalies in Cl p in the undercooled region are discussed in terms of structure and volume dependent contributions of energies and entropies.
| Original language | English |
|---|---|
| Pages (from-to) | 67-74 |
| Number of pages | 8 |
| Journal | Physics and Chemistry of Liquids |
| Volume | 36 |
| Issue number | 2 |
| Publication status | Published - 1998 |
Keywords
- Liquid metal Rb
- Specific heat
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Materials Chemistry
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Cite this
Singh, R. N., & Jaju, R. P. (1998). Undercooled state of liquid rubidium. Physics and Chemistry of Liquids, 36(2), 67-74.