Triplet states in a series of Pt-containing ethynylenes

J. S. Wilson; A. Köhler; R. H. Friend; M. K. Al-Suti; M. R.A. Al-Mandhary; M. S. Khan; P. R. Raithby

doi:10.1063/1.1313527

Triplet states in a series of Pt-containing ethynylenes

J. S. Wilson^*, A. Köhler, R. H. Friend, M. K. Al-Suti, M. R.A. Al-Mandhary, M. S. Khan, P. R. Raithby

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

155 Citations (Scopus)

Abstract

A model system was used where the triplet excited state has been made emissive thus rendering it easily accessible by optical spectroscopy to study the triplet excited state in conjugated polymers directly. This is achieved by including platinum in the main polymer chain. The heavy metal atom introduces spin-orbit coupling, and radiative transitions between singlet and triplet states become possible.

Original language	English
Pages (from-to)	7627-7634
Number of pages	8
Journal	Journal of Chemical Physics
Volume	113
Issue number	17
DOIs	https://doi.org/10.1063/1.1313527
Publication status	Published - Nov 1 2000

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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AU - Köhler, A.

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AU - Al-Mandhary, M. R.A.

AU - Khan, M. S.

AU - Raithby, P. R.

PY - 2000/11/1

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N2 - A model system was used where the triplet excited state has been made emissive thus rendering it easily accessible by optical spectroscopy to study the triplet excited state in conjugated polymers directly. This is achieved by including platinum in the main polymer chain. The heavy metal atom introduces spin-orbit coupling, and radiative transitions between singlet and triplet states become possible.

AB - A model system was used where the triplet excited state has been made emissive thus rendering it easily accessible by optical spectroscopy to study the triplet excited state in conjugated polymers directly. This is achieved by including platinum in the main polymer chain. The heavy metal atom introduces spin-orbit coupling, and radiative transitions between singlet and triplet states become possible.

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Triplet states in a series of Pt-containing ethynylenes

Abstract

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