Triplet states in a series of Pt-containing ethynylenes

J. S. Wilson, A. Köhler, R. H. Friend, M. K. Al-Suti, M. R A Al-Mandhary, M. S. Khan, P. R. Raithby

Research output: Contribution to journalArticle

142 Citations (Scopus)

Abstract

A model system was used where the triplet excited state has been made emissive thus rendering it easily accessible by optical spectroscopy to study the triplet excited state in conjugated polymers directly. This is achieved by including platinum in the main polymer chain. The heavy metal atom introduces spin-orbit coupling, and radiative transitions between singlet and triplet states become possible.

Original languageEnglish
Pages (from-to)7627-7634
Number of pages8
JournalJournal of Chemical Physics
Volume113
Issue number17
DOIs
Publication statusPublished - Nov 1 2000

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Excited states
atomic energy levels
Conjugated polymers
polymers
heavy metals
Heavy Metals
Platinum
excitation
Polymers
Orbits
platinum
orbits
Atoms
spectroscopy
atoms
Optical spectroscopy

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Wilson, J. S., Köhler, A., Friend, R. H., Al-Suti, M. K., Al-Mandhary, M. R. A., Khan, M. S., & Raithby, P. R. (2000). Triplet states in a series of Pt-containing ethynylenes. Journal of Chemical Physics, 113(17), 7627-7634. https://doi.org/10.1063/1.1313527

Triplet states in a series of Pt-containing ethynylenes. / Wilson, J. S.; Köhler, A.; Friend, R. H.; Al-Suti, M. K.; Al-Mandhary, M. R A; Khan, M. S.; Raithby, P. R.

In: Journal of Chemical Physics, Vol. 113, No. 17, 01.11.2000, p. 7627-7634.

Research output: Contribution to journalArticle

Wilson, JS, Köhler, A, Friend, RH, Al-Suti, MK, Al-Mandhary, MRA, Khan, MS & Raithby, PR 2000, 'Triplet states in a series of Pt-containing ethynylenes', Journal of Chemical Physics, vol. 113, no. 17, pp. 7627-7634. https://doi.org/10.1063/1.1313527
Wilson, J. S. ; Köhler, A. ; Friend, R. H. ; Al-Suti, M. K. ; Al-Mandhary, M. R A ; Khan, M. S. ; Raithby, P. R. / Triplet states in a series of Pt-containing ethynylenes. In: Journal of Chemical Physics. 2000 ; Vol. 113, No. 17. pp. 7627-7634.
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