Thermodynamic properties of CdNa alloys

Ritu; I. S. Jha; Bhrigunandan Prasad Singh; V. N. Choudhary; R. N. Singh

Thermodynamic properties of CdNa alloys

Ritu, I. S. Jha, Bhrigunandan Prasad Singh^*, V. N. Choudhary, R. N. Singh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The alloying behaviour of CdNa alloys is discussed on the basis of a simple theory based on the complex formation model. Though Cd and Na are simple metals but CdNa alloys exhibit anomalous behaviour. The excess free energy of mixing is negative in the region 0.6 ≤ C_Na > 0.1 and thereafter becomes positive. The concentration-concentration fluctuations in the long wavelength limit Scc(0) is larger than the ideal values Scc(0,id) up to C_cd = 0.55 and is less than ideal values for C_cd > 0.55. The concentration-dependent nature of asymmetry of the thermodynamic properties of mixing have been explained in this paper. The study reveals that Cd₂Na complex exists in the liquid phase close to melting temperature.

Original language	English
Pages (from-to)	635-637
Number of pages	3
Journal	Indian Journal of Physics
Volume	79
Issue number	6
Publication status	Published - Jun 2005
Externally published	Yes

Keywords

Cd Na alloys
Concentration-concentration fluctuations
Free energy of mixing
Thermodynamic properties
Volume of mixing

ASJC Scopus subject areas

General Physics and Astronomy

Cite this

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title = "Thermodynamic properties of CdNa alloys",

abstract = "The alloying behaviour of CdNa alloys is discussed on the basis of a simple theory based on the complex formation model. Though Cd and Na are simple metals but CdNa alloys exhibit anomalous behaviour. The excess free energy of mixing is negative in the region 0.6 ≤ CNa > 0.1 and thereafter becomes positive. The concentration-concentration fluctuations in the long wavelength limit Scc(0) is larger than the ideal values Scc(0,id) up to Ccd = 0.55 and is less than ideal values for Ccd > 0.55. The concentration-dependent nature of asymmetry of the thermodynamic properties of mixing have been explained in this paper. The study reveals that Cd2Na complex exists in the liquid phase close to melting temperature.",

keywords = "Cd Na alloys, Concentration-concentration fluctuations, Free energy of mixing, Thermodynamic properties, Volume of mixing",

author = "Ritu and Jha, {I. S.} and Singh, {Bhrigunandan Prasad} and Choudhary, {V. N.} and Singh, {R. N.}",

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language = "English",

volume = "79",

pages = "635--637",

journal = "Indian Journal of Physics",

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T1 - Thermodynamic properties of CdNa alloys

AU - Ritu,

AU - Jha, I. S.

AU - Singh, Bhrigunandan Prasad

AU - Choudhary, V. N.

AU - Singh, R. N.

PY - 2005/6

Y1 - 2005/6

N2 - The alloying behaviour of CdNa alloys is discussed on the basis of a simple theory based on the complex formation model. Though Cd and Na are simple metals but CdNa alloys exhibit anomalous behaviour. The excess free energy of mixing is negative in the region 0.6 ≤ CNa > 0.1 and thereafter becomes positive. The concentration-concentration fluctuations in the long wavelength limit Scc(0) is larger than the ideal values Scc(0,id) up to Ccd = 0.55 and is less than ideal values for Ccd > 0.55. The concentration-dependent nature of asymmetry of the thermodynamic properties of mixing have been explained in this paper. The study reveals that Cd2Na complex exists in the liquid phase close to melting temperature.

AB - The alloying behaviour of CdNa alloys is discussed on the basis of a simple theory based on the complex formation model. Though Cd and Na are simple metals but CdNa alloys exhibit anomalous behaviour. The excess free energy of mixing is negative in the region 0.6 ≤ CNa > 0.1 and thereafter becomes positive. The concentration-concentration fluctuations in the long wavelength limit Scc(0) is larger than the ideal values Scc(0,id) up to Ccd = 0.55 and is less than ideal values for Ccd > 0.55. The concentration-dependent nature of asymmetry of the thermodynamic properties of mixing have been explained in this paper. The study reveals that Cd2Na complex exists in the liquid phase close to melting temperature.

KW - Cd Na alloys

KW - Concentration-concentration fluctuations

KW - Free energy of mixing

KW - Thermodynamic properties

KW - Volume of mixing

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M3 - Article

AN - SCOPUS:22144435905

SN - 0252-9262

VL - 79

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JO - Indian Journal of Physics

JF - Indian Journal of Physics

IS - 6

ER -

Thermodynamic properties of CdNa alloys

Abstract

Keywords

ASJC Scopus subject areas

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