Thermo-elastic and thermodynamic properties of light and heavy crude oil

A. K. George, Naura Al-Majrafi, R. N. Singh, S. Arafin

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Three different experiments, viz., ultrasound interferometry, differential scanning calorimetry, and density measurements were carried out over a wide range of temperature varying from 20°C to 70°C in light, heavy, and a mixture of light and heavy crude oil samples which differ considerably in its American Petroleum Institute gravity. The properties of the mixture have been discussed in terms of its deviation from the ideal values of mixing. The directly measured quantities such as the compression wave velocity, the specific heat at constant pressure, and the density were used to evaluate the temperature dependence of adiabatic compressibility, coefficient of volume expansion and the acoustic impedance. A correlation between thermo-elastic and thermodynamic functions of crude oils has been investigated. In particular, the ratio of the specific heats has been determined by making use of the thermo-elastic functions, which was further used to estimate the specific heat at constant volume. The values of the isothermal compressibility and the coefficient of volume expansion are used to evaluate the pressure-temperature dependence of crude oil conforming to in-situ reservoir conditions.

Original languageEnglish
Pages (from-to)328-341
Number of pages14
JournalPhysics and Chemistry of Liquids
Volume46
Issue number3
DOIs
Publication statusPublished - Jun 2008

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Keywords

  • Compressibility
  • Equation of state
  • Specific heats
  • Ultrasound velocity

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials

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