Synthetic studies towards an advanced precursor of the jatrophane diterpene Pl-4

Rita Fürst, Christoph Lentsch, Uwe Rinner

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5 Citations (Scopus)

Abstract

Jatrophane diterpenes, isolated from members of the Euphorbiaceae plant family, constitute a class of biologically and structurally intriguing natural products. Herein, different strategies for the preparation of an advanced intermediate towards the total synthesis of the jatrophane diterpene Pl-4 are described. Key strategies for the elaboration of the jatrophane precursors include hydrometalation and radical reactions.

Original languageEnglish
Article numberSS-2013-T0694-OP
Pages (from-to)357-367
Number of pages11
JournalSynthesis (Germany)
Volume46
Issue number3
DOIs
Publication statusPublished - Feb 2014

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Keywords

  • Euphorbiaceae
  • hydrometalation
  • jatrophane diterpene
  • Reformatsky reaction
  • samarium diiodide

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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