Synthetic studies towards an advanced precursor of the jatrophane diterpene Pl-4

Rita Fürst; Christoph Lentsch; Uwe Rinner

doi:10.1055/s-0033-1338565

Synthetic studies towards an advanced precursor of the jatrophane diterpene Pl-4

Rita Fürst, Christoph Lentsch, Uwe Rinner^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Jatrophane diterpenes, isolated from members of the Euphorbiaceae plant family, constitute a class of biologically and structurally intriguing natural products. Herein, different strategies for the preparation of an advanced intermediate towards the total synthesis of the jatrophane diterpene Pl-4 are described. Key strategies for the elaboration of the jatrophane precursors include hydrometalation and radical reactions.

Original language	English
Article number	SS-2013-T0694-OP
Pages (from-to)	357-367
Number of pages	11
Journal	Synthesis (Germany)
Volume	46
Issue number	3
DOIs	https://doi.org/10.1055/s-0033-1338565
Publication status	Published - Feb 2014

Keywords

Euphorbiaceae
Reformatsky reaction
hydrometalation
jatrophane diterpene
samarium diiodide

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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abstract = "Jatrophane diterpenes, isolated from members of the Euphorbiaceae plant family, constitute a class of biologically and structurally intriguing natural products. Herein, different strategies for the preparation of an advanced intermediate towards the total synthesis of the jatrophane diterpene Pl-4 are described. Key strategies for the elaboration of the jatrophane precursors include hydrometalation and radical reactions.",

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KW - jatrophane diterpene

KW - samarium diiodide

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Synthetic studies towards an advanced precursor of the jatrophane diterpene Pl-4

Abstract

Keywords

ASJC Scopus subject areas

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