Synthesis of the C6-C14 Fragment of Euphosalicin

Christian Aichinger; Johann Mulzer; Uwe Rinner

doi:10.1055/s-0034-1380422

Synthesis of the C6-C14 Fragment of Euphosalicin

Christian Aichinger, Johann Mulzer, Uwe Rinner^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The synthesis of the C6-C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland-Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.

Original language	English
Article number	st-2015-b0256-l
Pages (from-to)	1852-1856
Number of pages	5
Journal	Synlett
Volume	26
Issue number	13
DOIs	https://doi.org/10.1055/s-0034-1380422
Publication status	Published - Aug 12 2015

Keywords

aldol reaction
hydrostannation
natural products
rearrangement
total synthesis

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0034-1380422

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title = "Synthesis of the C6-C14 Fragment of Euphosalicin",

abstract = "The synthesis of the C6-C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland-Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.",

keywords = "aldol reaction, hydrostannation, natural products, rearrangement, total synthesis",

author = "Christian Aichinger and Johann Mulzer and Uwe Rinner",

note = "Publisher Copyright: {\textcopyright} Georg Thieme Verlag Stuttgart · New York.",

year = "2015",

month = aug,

day = "12",

doi = "10.1055/s-0034-1380422",

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AU - Aichinger, Christian

AU - Mulzer, Johann

AU - Rinner, Uwe

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart · New York.

PY - 2015/8/12

Y1 - 2015/8/12

N2 - The synthesis of the C6-C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland-Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.

AB - The synthesis of the C6-C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland-Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.

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KW - hydrostannation

KW - natural products

KW - rearrangement

KW - total synthesis

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ER -

Synthesis of the C6-C14 Fragment of Euphosalicin

Abstract

Keywords

ASJC Scopus subject areas

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