Synthesis of the C6-C14 Fragment of Euphosalicin

Christian Aichinger, Johann Mulzer, Uwe Rinner

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The synthesis of the C6-C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland-Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.

Original languageEnglish
Article numberst-2015-b0256-l
Pages (from-to)1852-1856
Number of pages5
JournalSynlett
Volume26
Issue number13
DOIs
Publication statusPublished - Aug 12 2015

Fingerprint

Diterpenes
3-hydroxybutanal
jatrophane

Keywords

  • aldol reaction
  • hydrostannation
  • natural products
  • rearrangement
  • total synthesis

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Aichinger, C., Mulzer, J., & Rinner, U. (2015). Synthesis of the C6-C14 Fragment of Euphosalicin. Synlett, 26(13), 1852-1856. [st-2015-b0256-l]. https://doi.org/10.1055/s-0034-1380422

Synthesis of the C6-C14 Fragment of Euphosalicin. / Aichinger, Christian; Mulzer, Johann; Rinner, Uwe.

In: Synlett, Vol. 26, No. 13, st-2015-b0256-l, 12.08.2015, p. 1852-1856.

Research output: Contribution to journalArticle

Aichinger, C, Mulzer, J & Rinner, U 2015, 'Synthesis of the C6-C14 Fragment of Euphosalicin', Synlett, vol. 26, no. 13, st-2015-b0256-l, pp. 1852-1856. https://doi.org/10.1055/s-0034-1380422
Aichinger C, Mulzer J, Rinner U. Synthesis of the C6-C14 Fragment of Euphosalicin. Synlett. 2015 Aug 12;26(13):1852-1856. st-2015-b0256-l. https://doi.org/10.1055/s-0034-1380422
Aichinger, Christian ; Mulzer, Johann ; Rinner, Uwe. / Synthesis of the C6-C14 Fragment of Euphosalicin. In: Synlett. 2015 ; Vol. 26, No. 13. pp. 1852-1856.
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