Synthesis of the C6-C14 Fragment of Euphosalicin

Christian Aichinger, Johann Mulzer, Uwe Rinner

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Abstract

The synthesis of the C6-C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland-Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.

Original languageEnglish
Article numberst-2015-b0256-l
Pages (from-to)1852-1856
Number of pages5
JournalSynlett
Volume26
Issue number13
DOIs
Publication statusPublished - Aug 12 2015

Keywords

  • aldol reaction
  • hydrostannation
  • natural products
  • rearrangement
  • total synthesis

ASJC Scopus subject areas

  • Organic Chemistry

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  • Cite this

    Aichinger, C., Mulzer, J., & Rinner, U. (2015). Synthesis of the C6-C14 Fragment of Euphosalicin. Synlett, 26(13), 1852-1856. [st-2015-b0256-l]. https://doi.org/10.1055/s-0034-1380422