Abstract
Cationic [RuCl(arene)(Me-Duphos)]Cl complexes, arene=η6-benzene and η6-p-cymene, Me-Duphos=1,2-bis-((2R,5R)-2,5-dimethylphospholano) benzene) have been prepared and studied by X-ray crystallography and NMR spectroscopy. PGSE NMR diffusion studies have been used to recognize (a) ion pairing as a function of solvent and (b) larger molecular volumes. Several arene-Ru-complexes have been shown to be useful catalyst precursors in the hydrolysis of terminal aryl alkynes to afford acetophenones.
| Original language | English |
|---|---|
| Pages (from-to) | 4-14 |
| Number of pages | 11 |
| Journal | Inorganica Chimica Acta |
| Volume | 327 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 10 2002 |
Keywords
- Diffusion and catalytic studies
- Me-Duphos
- PGSE
- Ru-Arene complexes
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Cite this
Chen, Y., Valentini, M., Pregosin, P. S., & Albinati, A. (2002). Synthesis of Ru-Arene complexes of Me-Duphos. X-ray, PGSE NMR diffusion and catalytic studies. Inorganica Chimica Acta, 327(1), 4-14. https://doi.org/10.1016/S0020-1693(01)00680-6