TY - JOUR
T1 - Synthesis of novel rigid rod iron metal containing polyyne polymers
AU - Johnson, Brian F.G.
AU - Kakkar, Ashok K.
AU - Khan, Muhammad S.
AU - Lewis, Jack
N1 - Funding Information:
Acknowledgements. We thank the NSERC of Canada for a post-doctoral fellowship to A.K. Kakkar, SERC for financial support, and Dhaka University (Bangladesh) for study leave to M.S. Khan. We also thank Prof. Todd B. Marder of University of Waterloo (Canada) for helpful discussions, and Dr. Elizabeth Meehan at Polymer Laboratories (UK) for molecular weight determinations.
PY - 1991/6/4
Y1 - 1991/6/4
N2 - Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).
AB - Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).
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U2 - 10.1016/0022-328X(91)80028-I
DO - 10.1016/0022-328X(91)80028-I
M3 - Article
AN - SCOPUS:0002243041
SN - 0022-328X
VL - 409
SP - C12-C14
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 3
ER -