Synthesis of novel rigid rod iron metal containing polyyne polymers

Brian F G Johnson, Ashok K. Kakkar, Muhammad S. Khan, Jack Lewis

Research output: Contribution to journalArticle

75 Citations (Scopus)

Abstract

Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).

Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume409
Issue number3
DOIs
Publication statusPublished - Jun 4 1991

Fingerprint

phosphine
Chelation
phosphines
molecular weight
Polymers
rods
Iron
Molecular Weight
Metals
Molecular weight
iron
polymers
synthesis
metals

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Synthesis of novel rigid rod iron metal containing polyyne polymers. / Johnson, Brian F G; Kakkar, Ashok K.; Khan, Muhammad S.; Lewis, Jack.

In: Journal of Organometallic Chemistry, Vol. 409, No. 3, 04.06.1991.

Research output: Contribution to journalArticle

Johnson, Brian F G ; Kakkar, Ashok K. ; Khan, Muhammad S. ; Lewis, Jack. / Synthesis of novel rigid rod iron metal containing polyyne polymers. In: Journal of Organometallic Chemistry. 1991 ; Vol. 409, No. 3.
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