Abstract
Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).
Original language | English |
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Journal | Journal of Organometallic Chemistry |
Volume | 409 |
Issue number | 3 |
DOIs | |
Publication status | Published - Jun 4 1991 |
ASJC Scopus subject areas
- Biochemistry
- Chemical Engineering (miscellaneous)
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Science (miscellaneous)
- Materials Chemistry