Synthesis of novel rigid rod iron metal containing polyyne polymers

Brian F G Johnson; Ashok K. Kakkar; Muhammad S. Khan; Jack Lewis

doi:10.1016/0022-328X(91)80028-I

Synthesis of novel rigid rod iron metal containing polyyne polymers

Brian F G Johnson^*, Ashok K. Kakkar, Muhammad S. Khan, Jack Lewis

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

76 Citations (Scopus)

Abstract

Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)₂Cl₂ (1) with 2.5 equivalents of Me₃SnCC₆H₅ (2) gives the monomeric complex, tras-Fe(DEPE)₂(CCC₆H₅)₂ (3, whereas the reaction of equimolar quantities of 1 and Me₃SnCCRCCSnMe₃ (R = p-C₆H₄ (4); p-C₃)₂C₆H₂ (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)₂(-CCRCC-)]_n (6,7).

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	409
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(91)80028-I
Publication status	Published - Jun 4 1991

ASJC Scopus subject areas

Biochemistry
Chemical Engineering (miscellaneous)
Inorganic Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Materials Chemistry

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title = "Synthesis of novel rigid rod iron metal containing polyyne polymers",

abstract = "Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).",

author = "Johnson, {Brian F G} and Kakkar, {Ashok K.} and Khan, {Muhammad S.} and Jack Lewis",

year = "1991",

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T1 - Synthesis of novel rigid rod iron metal containing polyyne polymers

AU - Johnson, Brian F G

AU - Kakkar, Ashok K.

AU - Khan, Muhammad S.

AU - Lewis, Jack

PY - 1991/6/4

Y1 - 1991/6/4

N2 - Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).

AB - Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).

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