Synthesis of novel rigid rod iron metal containing polyyne polymers

Brian F G Johnson; Ashok K. Kakkar; Muhammad S. Khan; Jack Lewis

doi:10.1016/0022-328X(91)80028-I

Synthesis of novel rigid rod iron metal containing polyyne polymers

Brian F G Johnson, Ashok K. Kakkar, Muhammad S. Khan, Jack Lewis

Chemistry

Research output: Contribution to journal › Article

75 Citations (Scopus)

Abstract

Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)₂Cl₂ (1) with 2.5 equivalents of Me₃SnCC₆H₅ (2) gives the monomeric complex, tras-Fe(DEPE)₂(CCC₆H₅)₂ (3, whereas the reaction of equimolar quantities of 1 and Me₃SnCCRCCSnMe₃ (R = p-C₆H₄ (4); p-C₃)₂C₆H₂ (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)₂(-CCRCC-)]_n (6,7).

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	409
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(91)80028-I
Publication status	Published - Jun 4 1991

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ASJC Scopus subject areas

Biochemistry
Chemical Engineering (miscellaneous)
Inorganic Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Materials Chemistry

Cite this

Johnson, B. F. G., Kakkar, A. K., Khan, M. S., & Lewis, J. (1991). Synthesis of novel rigid rod iron metal containing polyyne polymers. Journal of Organometallic Chemistry, 409(3). https://doi.org/10.1016/0022-328X(91)80028-I

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abstract = "Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).",

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N2 - Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).

AB - Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnCC6H5 (2) gives the monomeric complex, tras-Fe(DEPE)2(CCC6H5)2 (3, whereas the reaction of equimolar quantities of 1 and Me3SnCCRCCSnMe3 (R = p-C6H4 (4); p-C3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-CCRCC-)]n (6,7).

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10.1016/0022-328X(91)80028-I