Synthesis of cross linked platinum metal containing polyyne polymers

M. S. Khan; D. J. Schwartz; N. A. Pasha; A. K. Kakkar; B. Lin; P. R. Raithby; J. Lewis

doi:10.1002/zaac.19926161018

Synthesis of cross linked platinum metal containing polyyne polymers

M. S. Khan, D. J. Schwartz, N. A. Pasha, A. K. Kakkar, B. Lin, P. R. Raithby, J. Lewis^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Reaction of Pt(PⁿBu₃)₂Cl₂ (1) or Pt(AsⁿBu₃₂Cl₂ (2) with stoichiometric amounts of 1,3,5‐triethynylbenzene, [1,3,5‐(HCC)₃C₆H₃] (3)yields monomeric, [1,3,5‐Cl(PⁿBu₃)₂(PtC C)₃C₆H₃] (4), [1,3,5‐(C1)(AsⁿBu₃)₂PtC C₃C₆H₃] (5) or polymeric, {1,3,5‐[(PⁿBu₃)₂PtCC]₃C₆H₃)ⁿ (6), {1,3,5‐[(AsⁿBu₃)₂PtC C]₃C₆H₃}ⁿ (7) complexes. Treatment of (1) with (3) and 2,5‐diethynyl‐p‐xylene,HC CC₆H₂(CH₃)₂C CH (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.

Original language	English
Pages (from-to)	121-124
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	616
Issue number	10
DOIs	https://doi.org/10.1002/zaac.19926161018
Publication status	Published - 1992
Externally published	Yes

Keywords

cross‐linked
electronic properties
polyyne copolymer
rigid‐rod
π‐conjugation
σ‐acetylide

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/zaac.19926161018

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@article{af792d1647da4657a9770f0e83056e62,

title = "Synthesis of cross linked platinum metal containing polyyne polymers",

abstract = "Reaction of Pt(PnBu3)2Cl2 (1) or Pt(AsnBu32Cl2 (2) with stoichiometric amounts of 1,3,5‐triethynylbenzene, [1,3,5‐(HCC)3C6H3] (3)yields monomeric, [1,3,5‐Cl(PnBu3)2(PtC C)3C6H3] (4), [1,3,5‐(C1)(AsnBu3)2PtC C3C6H3] (5) or polymeric, {1,3,5‐[(PnBu3)2PtCC]3C6H3)n (6), {1,3,5‐[(AsnBu3)2PtC C]3C6H3}n (7) complexes. Treatment of (1) with (3) and 2,5‐diethynyl‐p‐xylene,HC CC6H2(CH3)2C CH (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.",

keywords = "cross‐linked, electronic properties, polyyne copolymer, rigid‐rod, π‐conjugation, σ‐acetylide",

author = "Khan, {M. S.} and Schwartz, {D. J.} and Pasha, {N. A.} and Kakkar, {A. K.} and B. Lin and Raithby, {P. R.} and J. Lewis",

year = "1992",

doi = "10.1002/zaac.19926161018",

language = "English",

volume = "616",

pages = "121--124",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "10",

}

TY - JOUR

T1 - Synthesis of cross linked platinum metal containing polyyne polymers

AU - Khan, M. S.

AU - Schwartz, D. J.

AU - Pasha, N. A.

AU - Kakkar, A. K.

AU - Lin, B.

AU - Raithby, P. R.

AU - Lewis, J.

PY - 1992

Y1 - 1992

N2 - Reaction of Pt(PnBu3)2Cl2 (1) or Pt(AsnBu32Cl2 (2) with stoichiometric amounts of 1,3,5‐triethynylbenzene, [1,3,5‐(HCC)3C6H3] (3)yields monomeric, [1,3,5‐Cl(PnBu3)2(PtC C)3C6H3] (4), [1,3,5‐(C1)(AsnBu3)2PtC C3C6H3] (5) or polymeric, {1,3,5‐[(PnBu3)2PtCC]3C6H3)n (6), {1,3,5‐[(AsnBu3)2PtC C]3C6H3}n (7) complexes. Treatment of (1) with (3) and 2,5‐diethynyl‐p‐xylene,HC CC6H2(CH3)2C CH (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.

AB - Reaction of Pt(PnBu3)2Cl2 (1) or Pt(AsnBu32Cl2 (2) with stoichiometric amounts of 1,3,5‐triethynylbenzene, [1,3,5‐(HCC)3C6H3] (3)yields monomeric, [1,3,5‐Cl(PnBu3)2(PtC C)3C6H3] (4), [1,3,5‐(C1)(AsnBu3)2PtC C3C6H3] (5) or polymeric, {1,3,5‐[(PnBu3)2PtCC]3C6H3)n (6), {1,3,5‐[(AsnBu3)2PtC C]3C6H3}n (7) complexes. Treatment of (1) with (3) and 2,5‐diethynyl‐p‐xylene,HC CC6H2(CH3)2C CH (8) in varying molar ratios yields a series of high molecular weight cross linked platinum metal containing polyyne copolymers.

KW - cross‐linked

KW - electronic properties

KW - polyyne copolymer

KW - rigid‐rod

KW - π‐conjugation

KW - σ‐acetylide

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U2 - 10.1002/zaac.19926161018

DO - 10.1002/zaac.19926161018

M3 - Article

AN - SCOPUS:84984051908

SN - 0044-2313

VL - 616

SP - 121

EP - 124

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 10

ER -

Synthesis of cross linked platinum metal containing polyyne polymers

Abstract

Keywords

ASJC Scopus subject areas

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