Synthesis and structural characterisation of [Os4H2(CO) 11{Au2(DPPM)}2]: The first cluster with an Os4Au4 core

Muna R.A. Al-Mandhary, Jack Lewis, Paul R. Raithby

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8 Citations (Scopus)

Abstract

The reaction of the dianion [Os4H2(CO)11]2- with two equivalents of Au2(DPPM)Cl2 (DPPM = Ph2PCH2PPh2), in the presence of Tl[PF6], affords a digold species which upon treatment with NEt3 gives the neutral cluster [Os4H2(CO)11{Au2(DPPM)}2]. This cluster has been characterised by 1H and 31P NMR spectroscopy, mass spectrometry and X-ray crystallography. The metal core consists of an Os4 tetrahedron, one face of which is capped by three Au atoms while the fourth Au atom caps an OsAu2 face.

Original languageEnglish
Pages (from-to)549-551
Number of pages3
JournalJournal of Organometallic Chemistry
Volume536-537
Publication statusPublished - May 30 1997

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Keywords

  • Carbonyl
  • Cluster
  • Crystal structure
  • Gold
  • Osmium
  • Phosphine

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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