Synthesis and optical spectroscopy of monomeric and polymeric cobalt σ-acetylide complexes

Muhammad S. Khan, Nishat A. Pasha, Ashok K. Kakkar, Paul R. Raithby, Jack Lewis*, Klaus Fuhrmann, Richard H. Friend

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)

Abstract

Optical spectra of the complexes, trans-CICoN4C≡CC6H5 trans-CoN4(C≡CC6H5)2 and [-CoN4C≡C-p-C6H4C≡C-]n, (where N4 = 3,9-dimethyl-4,8-diazaundecane-2,10-dione dioxime) show absorptions associated with π-π*transitions of the acetylenic unit and indicate an extended π-electron conjugation through the metal sites on the chain in the polymeric complex.

Original languageEnglish
Pages (from-to)759-760
Number of pages2
JournalJournal of Materials Chemistry
Volume2
Issue number7
DOIs
Publication statusPublished - 1992

Keywords

  • Energy gap
  • Optical absorption
  • π-Electron conjugation
  • σ-Acetylide

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Chemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry

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