Synthesis and characterisation of monomeric, dimeric and polymeric ferrocenylacetylides. Crystal structure of 1,1′-bis(phenylethynyl)ferrocene

Scott L. Ingham; Muhammad S. Khan; Jack Lewis; Nicholas J. Long; Paul R. Raithby

doi:10.1016/0022-328X(94)80160-6

Synthesis and characterisation of monomeric, dimeric and polymeric ferrocenylacetylides. Crystal structure of 1,1′-bis(phenylethynyl)ferrocene

Scott L. Ingham^*, Muhammad S. Khan, Jack Lewis, Nicholas J. Long, Paul R. Raithby

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

The reactions of alkynyltrimethylstannanes with 1,1′-dilithioferrocene have given several ferrocenylacetylides, namely 1-pheny]-ethynyl-1′-iodo-ferrocene (1), 1,1′-bis(phenylethynyl)ferrocene (2), 1,4-di(1′-iodoferrocenylethynyl)benzene (3) and poly[1,4-(1′-ferrocenylethynyl)ethynylbenzene] (4). The versatility of this reaction for the formation of ferrocenylacetylides is demonstrated. The crystal structure of 2 has been determined, and shown to involve a linear array of the groups with a cis arrangement of the phenylethynyl ligands.

Original language	English
Pages (from-to)	153-159
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	470
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)80160-6
Publication status	Published - May 17 1994
Externally published	Yes

Keywords

Alkyne
Crystal structure
Ferrocene
Polymer
Tin

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(94)80160-6

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@article{2e2a5eb90f48459b9c1449feb7b070aa,

title = "Synthesis and characterisation of monomeric, dimeric and polymeric ferrocenylacetylides. Crystal structure of 1,1′-bis(phenylethynyl)ferrocene",

abstract = "The reactions of alkynyltrimethylstannanes with 1,1′-dilithioferrocene have given several ferrocenylacetylides, namely 1-pheny]-ethynyl-1′-iodo-ferrocene (1), 1,1′-bis(phenylethynyl)ferrocene (2), 1,4-di(1′-iodoferrocenylethynyl)benzene (3) and poly[1,4-(1′-ferrocenylethynyl)ethynylbenzene] (4). The versatility of this reaction for the formation of ferrocenylacetylides is demonstrated. The crystal structure of 2 has been determined, and shown to involve a linear array of the groups with a cis arrangement of the phenylethynyl ligands.",

keywords = "Alkyne, Crystal structure, Ferrocene, Polymer, Tin",

author = "Ingham, {Scott L.} and Khan, {Muhammad S.} and Jack Lewis and Long, {Nicholas J.} and Raithby, {Paul R.}",

note = "Funding Information: We wish to thank Darwin College, Cambridgef or the award of the Adrian Research Fellowship (to N.J.L.), the SERC (M.S.K., S.L.I.) and Kobe Steel, Europe Ltd. (M.S.K.) for financial support, and the University of Dhaka, Bangladeshf or study leave (to M.S.K.). We also thank Dr. I. Hinton at Ciba-Geigy Plastics (UK) for determination of the molecular weights,a nd Professor D. Cardin for helpful discussions.",

year = "1994",

month = may,

day = "17",

doi = "10.1016/0022-328X(94)80160-6",

language = "English",

volume = "470",

pages = "153--159",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

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TY - JOUR

T1 - Synthesis and characterisation of monomeric, dimeric and polymeric ferrocenylacetylides. Crystal structure of 1,1′-bis(phenylethynyl)ferrocene

AU - Ingham, Scott L.

AU - Khan, Muhammad S.

AU - Lewis, Jack

AU - Long, Nicholas J.

AU - Raithby, Paul R.

N1 - Funding Information: We wish to thank Darwin College, Cambridgef or the award of the Adrian Research Fellowship (to N.J.L.), the SERC (M.S.K., S.L.I.) and Kobe Steel, Europe Ltd. (M.S.K.) for financial support, and the University of Dhaka, Bangladeshf or study leave (to M.S.K.). We also thank Dr. I. Hinton at Ciba-Geigy Plastics (UK) for determination of the molecular weights,a nd Professor D. Cardin for helpful discussions.

PY - 1994/5/17

Y1 - 1994/5/17

N2 - The reactions of alkynyltrimethylstannanes with 1,1′-dilithioferrocene have given several ferrocenylacetylides, namely 1-pheny]-ethynyl-1′-iodo-ferrocene (1), 1,1′-bis(phenylethynyl)ferrocene (2), 1,4-di(1′-iodoferrocenylethynyl)benzene (3) and poly[1,4-(1′-ferrocenylethynyl)ethynylbenzene] (4). The versatility of this reaction for the formation of ferrocenylacetylides is demonstrated. The crystal structure of 2 has been determined, and shown to involve a linear array of the groups with a cis arrangement of the phenylethynyl ligands.

AB - The reactions of alkynyltrimethylstannanes with 1,1′-dilithioferrocene have given several ferrocenylacetylides, namely 1-pheny]-ethynyl-1′-iodo-ferrocene (1), 1,1′-bis(phenylethynyl)ferrocene (2), 1,4-di(1′-iodoferrocenylethynyl)benzene (3) and poly[1,4-(1′-ferrocenylethynyl)ethynylbenzene] (4). The versatility of this reaction for the formation of ferrocenylacetylides is demonstrated. The crystal structure of 2 has been determined, and shown to involve a linear array of the groups with a cis arrangement of the phenylethynyl ligands.

KW - Alkyne

KW - Crystal structure

KW - Ferrocene

KW - Polymer

KW - Tin

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U2 - 10.1016/0022-328X(94)80160-6

DO - 10.1016/0022-328X(94)80160-6

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AN - SCOPUS:0000456331

SN - 0022-328X

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SP - 153

EP - 159

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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ER -

Synthesis and characterisation of monomeric, dimeric and polymeric ferrocenylacetylides. Crystal structure of 1,1′-bis(phenylethynyl)ferrocene

Abstract

Keywords

ASJC Scopus subject areas

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