Sulfonated mesoporous zinc aluminate catalyst for biodiesel production from high free fatty acid feedstock using microwave heating system

Soroush Soltani, Umer Rashid, Imededdine Arbi Nehdi, Saud Ibrahim Al-Resayes, Ala'a H. Al-Muhtaseb

Research output: Contribution to journalArticle

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Abstract

Methyl ester was derived from one-step esterification of palm fatty acid distillate (PFAD) in presence of mesoporous SO3H–ZnAl2O4 solid acid catalyst using microwave irradiation heating system. The catalyst characteristics were studied by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FT-IR), temperature programmed desorption (TPD) and thermogravimetric analysis (TGA). The mesoporous SO3H–ZnAl2O4 catalyst possessed unique properties such as surface area of 376.26 m2 g−1, total pore volume of 0.16 cm3 g−1, an average pore diameter of 3.55 nm and an acid density of 2.10 mmol g−1. A sequence of experiments were carried out in order to assess the influence of reaction parameters as follows: catalyst concentration (0.5–3.0 wt%), methanol to oil molar ratio (3:1–15:1), reaction temperature (50–70 °C), and mixing intensity (200–500 rpm) for methyl ester production. The evaluation of the esterification was conducted by gas chromatographic (GC) analysis of the PFAD methyl ester at various reaction times. The highest FAME yield was achieved (94.59%) at 20 min under optimum esterification condition (catalyst concentration of 1.5 wt%, methanol to PFAD molar ratio of 9:1, reaction temperature of 60 °C, and mixing intensity of 300 rpm using microwave irradiation heating system. The recyclability experiments revealed that the synthesized catalyst was potential to stay stable for eight consecutive reaction runs with only 22.55% drop in ester synthesis. The quality of the produced ester was assessed by determination of some key fuel properties such as density, acid value, kinematic viscosity, water content, pour point, could point, and flash point. The PFAD methyl ester was establish to satisfy those of European (EN 14214) and American Standards for Testing Materials (ASTM) specifications.

Original languageEnglish
Pages (from-to)219-228
Number of pages10
JournalJournal of the Taiwan Institute of Chemical Engineers
Volume70
DOIs
Publication statusPublished - Jan 1 2017

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Microwave heating
Biofuels
Biodiesel
Fatty acids
Nonesterified Fatty Acids
Feedstocks
Zinc
Esters
Catalysts
Esterification
Fatty Acids
Microwave irradiation
Acids
Methanol
Heating
Materials testing
Temperature programmed desorption
Gas chromatography
Water content
Fourier transform infrared spectroscopy

Keywords

  • Esterification
  • Fuel properties
  • Microwave irradiation heating system
  • Palm fatty acid distillate
  • Sulfonated zinc aluminate catalyst

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Sulfonated mesoporous zinc aluminate catalyst for biodiesel production from high free fatty acid feedstock using microwave heating system. / Soltani, Soroush; Rashid, Umer; Nehdi, Imededdine Arbi; Al-Resayes, Saud Ibrahim; Al-Muhtaseb, Ala'a H.

In: Journal of the Taiwan Institute of Chemical Engineers, Vol. 70, 01.01.2017, p. 219-228.

Research output: Contribution to journalArticle

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abstract = "Methyl ester was derived from one-step esterification of palm fatty acid distillate (PFAD) in presence of mesoporous SO3H–ZnAl2O4 solid acid catalyst using microwave irradiation heating system. The catalyst characteristics were studied by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FT-IR), temperature programmed desorption (TPD) and thermogravimetric analysis (TGA). The mesoporous SO3H–ZnAl2O4 catalyst possessed unique properties such as surface area of 376.26 m2 g−1, total pore volume of 0.16 cm3 g−1, an average pore diameter of 3.55 nm and an acid density of 2.10 mmol g−1. A sequence of experiments were carried out in order to assess the influence of reaction parameters as follows: catalyst concentration (0.5–3.0 wt{\%}), methanol to oil molar ratio (3:1–15:1), reaction temperature (50–70 °C), and mixing intensity (200–500 rpm) for methyl ester production. The evaluation of the esterification was conducted by gas chromatographic (GC) analysis of the PFAD methyl ester at various reaction times. The highest FAME yield was achieved (94.59{\%}) at 20 min under optimum esterification condition (catalyst concentration of 1.5 wt{\%}, methanol to PFAD molar ratio of 9:1, reaction temperature of 60 °C, and mixing intensity of 300 rpm using microwave irradiation heating system. The recyclability experiments revealed that the synthesized catalyst was potential to stay stable for eight consecutive reaction runs with only 22.55{\%} drop in ester synthesis. The quality of the produced ester was assessed by determination of some key fuel properties such as density, acid value, kinematic viscosity, water content, pour point, could point, and flash point. The PFAD methyl ester was establish to satisfy those of European (EN 14214) and American Standards for Testing Materials (ASTM) specifications.",
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AU - Al-Resayes, Saud Ibrahim

AU - Al-Muhtaseb, Ala'a H.

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N2 - Methyl ester was derived from one-step esterification of palm fatty acid distillate (PFAD) in presence of mesoporous SO3H–ZnAl2O4 solid acid catalyst using microwave irradiation heating system. The catalyst characteristics were studied by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FT-IR), temperature programmed desorption (TPD) and thermogravimetric analysis (TGA). The mesoporous SO3H–ZnAl2O4 catalyst possessed unique properties such as surface area of 376.26 m2 g−1, total pore volume of 0.16 cm3 g−1, an average pore diameter of 3.55 nm and an acid density of 2.10 mmol g−1. A sequence of experiments were carried out in order to assess the influence of reaction parameters as follows: catalyst concentration (0.5–3.0 wt%), methanol to oil molar ratio (3:1–15:1), reaction temperature (50–70 °C), and mixing intensity (200–500 rpm) for methyl ester production. The evaluation of the esterification was conducted by gas chromatographic (GC) analysis of the PFAD methyl ester at various reaction times. The highest FAME yield was achieved (94.59%) at 20 min under optimum esterification condition (catalyst concentration of 1.5 wt%, methanol to PFAD molar ratio of 9:1, reaction temperature of 60 °C, and mixing intensity of 300 rpm using microwave irradiation heating system. The recyclability experiments revealed that the synthesized catalyst was potential to stay stable for eight consecutive reaction runs with only 22.55% drop in ester synthesis. The quality of the produced ester was assessed by determination of some key fuel properties such as density, acid value, kinematic viscosity, water content, pour point, could point, and flash point. The PFAD methyl ester was establish to satisfy those of European (EN 14214) and American Standards for Testing Materials (ASTM) specifications.

AB - Methyl ester was derived from one-step esterification of palm fatty acid distillate (PFAD) in presence of mesoporous SO3H–ZnAl2O4 solid acid catalyst using microwave irradiation heating system. The catalyst characteristics were studied by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FT-IR), temperature programmed desorption (TPD) and thermogravimetric analysis (TGA). The mesoporous SO3H–ZnAl2O4 catalyst possessed unique properties such as surface area of 376.26 m2 g−1, total pore volume of 0.16 cm3 g−1, an average pore diameter of 3.55 nm and an acid density of 2.10 mmol g−1. A sequence of experiments were carried out in order to assess the influence of reaction parameters as follows: catalyst concentration (0.5–3.0 wt%), methanol to oil molar ratio (3:1–15:1), reaction temperature (50–70 °C), and mixing intensity (200–500 rpm) for methyl ester production. The evaluation of the esterification was conducted by gas chromatographic (GC) analysis of the PFAD methyl ester at various reaction times. The highest FAME yield was achieved (94.59%) at 20 min under optimum esterification condition (catalyst concentration of 1.5 wt%, methanol to PFAD molar ratio of 9:1, reaction temperature of 60 °C, and mixing intensity of 300 rpm using microwave irradiation heating system. The recyclability experiments revealed that the synthesized catalyst was potential to stay stable for eight consecutive reaction runs with only 22.55% drop in ester synthesis. The quality of the produced ester was assessed by determination of some key fuel properties such as density, acid value, kinematic viscosity, water content, pour point, could point, and flash point. The PFAD methyl ester was establish to satisfy those of European (EN 14214) and American Standards for Testing Materials (ASTM) specifications.

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