TY - JOUR
T1 - Structural characterisation of a pentagonal bipyramidal macrocyclic chromium(III) complex; an explanation of a chromium-mediated 'transient-template' effect
AU - Chung, L. Y.
AU - Constable, Edwin C.
AU - Khan, Mohammed S.
AU - Lewis, Jack
AU - Raithby, Paul R.
AU - Vargas, Maria D.
PY - 1984
Y1 - 1984
N2 - The template condensation of 6,6'-bis(hydrazino)-2,2'-bipyridines or 2,9-bis(hydrazino)-1,10-phenanthrolines with 2,6-pyridine dicarbonyls in the presence of chromium(III) chloride leads to the formation of free macrocycles rather than the expected metal complexes; the origin of this 'transient-template' effect is discussed and the crystal structural analysis of a chromium(III) macrocyclic complex is described.
AB - The template condensation of 6,6'-bis(hydrazino)-2,2'-bipyridines or 2,9-bis(hydrazino)-1,10-phenanthrolines with 2,6-pyridine dicarbonyls in the presence of chromium(III) chloride leads to the formation of free macrocycles rather than the expected metal complexes; the origin of this 'transient-template' effect is discussed and the crystal structural analysis of a chromium(III) macrocyclic complex is described.
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U2 - 10.1039/C39840001425
DO - 10.1039/C39840001425
M3 - Article
AN - SCOPUS:37049108396
SN - 0022-4936
SP - 1425
EP - 1426
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 21
ER -