Abstract
The alloying behaviour of HgNa and HgK liquid alloys has been investigated by assuming that the chemical complexes Hg2Na and Hg2K exist near the melting point on the molten amalgams. This has been used to obtain the concentration dependence of the free energy of mixing, activity, long-wavelength fluctuations and the volume of mixing. The results reveal that HgNa liquid alloys are more stable than HgK at all concentrations. There is every likelihood of the existence of Hg2Na and Hg2K complexes in the liquid alloys.
| Original language | English |
|---|---|
| Pages (from-to) | 15-24 |
| Number of pages | 10 |
| Journal | Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties |
| Volume | 61 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1990 |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Chemical Engineering(all)
- Engineering(all)
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Jha, I. S., Singh, R. N., Srivastava, P. L., & Mitra, N. R. (1990). Stability of HgNa and HgK liquid alloys. Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties, 61(1), 15-24. https://doi.org/10.1080/13642819008208649