Abstract
The alloying behaviour of HgNa and HgK liquid alloys has been investigated by assuming that the chemical complexes Hg2Na and Hg2K exist near the melting point on the molten amalgams. This has been used to obtain the concentration dependence of the free energy of mixing, activity, long-wavelength fluctuations and the volume of mixing. The results reveal that HgNa liquid alloys are more stable than HgK at all concentrations. There is every likelihood of the existence of Hg2Na and Hg2K complexes in the liquid alloys.
| Original language | English |
|---|---|
| Pages (from-to) | 15-24 |
| Number of pages | 10 |
| Journal | Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties |
| Volume | 61 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1990 |
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ASJC Scopus subject areas
- Physics and Astronomy(all)
- Chemical Engineering(all)
- Engineering(all)
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Stability of HgNa and HgK liquid alloys. / Jha, I. S.; Singh, R. N.; Srivastava, P. L.; Mitra, N. R.
In: Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties, Vol. 61, No. 1, 1990, p. 15-24.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Stability of HgNa and HgK liquid alloys
AU - Jha, I. S.
AU - Singh, R. N.
AU - Srivastava, P. L.
AU - Mitra, N. R.
PY - 1990
Y1 - 1990
N2 - The alloying behaviour of HgNa and HgK liquid alloys has been investigated by assuming that the chemical complexes Hg2Na and Hg2K exist near the melting point on the molten amalgams. This has been used to obtain the concentration dependence of the free energy of mixing, activity, long-wavelength fluctuations and the volume of mixing. The results reveal that HgNa liquid alloys are more stable than HgK at all concentrations. There is every likelihood of the existence of Hg2Na and Hg2K complexes in the liquid alloys.
AB - The alloying behaviour of HgNa and HgK liquid alloys has been investigated by assuming that the chemical complexes Hg2Na and Hg2K exist near the melting point on the molten amalgams. This has been used to obtain the concentration dependence of the free energy of mixing, activity, long-wavelength fluctuations and the volume of mixing. The results reveal that HgNa liquid alloys are more stable than HgK at all concentrations. There is every likelihood of the existence of Hg2Na and Hg2K complexes in the liquid alloys.
UR - http://www.scopus.com/inward/record.url?scp=0025233291&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0025233291&partnerID=8YFLogxK
U2 - 10.1080/13642819008208649
DO - 10.1080/13642819008208649
M3 - Article
AN - SCOPUS:0025233291
VL - 61
SP - 15
EP - 24
JO - Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties
JF - Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties
SN - 1364-2812
IS - 1
ER -