Solubility of sodium salts in ammonium-based deep eutectic solvents

Fatemeh Saadat Ghareh Bagh, Farouq S. Mjalli, Mohd Ali Hashim, Mohamed Kamel Omar Hadj-Kali, Inas M. Alnashef

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

The solubility of sodium chloride (NaCl), sodium bromide (NaBr), and sodium carbonate (Na2CO3) was measured in nine ammonium-based deep eutectic solvents (DESs). The aim of the study is to assess the potential use of these DESs as solvents and electrolytes for the separation of sodium metal from its salts. The studied DESs were prepared by combining ammonium salts with various hydrogen-bond donors (HBDs) or metal halides. It was found that the solubility of the sodium salts in DESs increases with temperature in many cases. The maximum solubility of NaCl achieved was 100 w = 80 in N,N-diethylethanolammonium chloride:zinc(II) chloride (molar ratio 1:3) at 90 C. In addition, the solubility of the sodium salts was modeled successfully using the non-random two liquid (NRTL) model.

Original languageEnglish
Pages (from-to)2154-2162
Number of pages9
JournalJournal of Chemical and Engineering Data
Volume58
Issue number8
DOIs
Publication statusPublished - Aug 8 2013

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Ammonium Compounds
Eutectics
Solubility
Salts
Sodium
Metal halides
Zinc chloride
Sodium chloride
Sodium Chloride
Electrolytes
Carbonates
Hydrogen bonds
Metals
Liquids
Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Ghareh Bagh, F. S., Mjalli, F. S., Hashim, M. A., Hadj-Kali, M. K. O., & Alnashef, I. M. (2013). Solubility of sodium salts in ammonium-based deep eutectic solvents. Journal of Chemical and Engineering Data, 58(8), 2154-2162. https://doi.org/10.1021/je400045d

Solubility of sodium salts in ammonium-based deep eutectic solvents. / Ghareh Bagh, Fatemeh Saadat; Mjalli, Farouq S.; Hashim, Mohd Ali; Hadj-Kali, Mohamed Kamel Omar; Alnashef, Inas M.

In: Journal of Chemical and Engineering Data, Vol. 58, No. 8, 08.08.2013, p. 2154-2162.

Research output: Contribution to journalArticle

Ghareh Bagh, FS, Mjalli, FS, Hashim, MA, Hadj-Kali, MKO & Alnashef, IM 2013, 'Solubility of sodium salts in ammonium-based deep eutectic solvents', Journal of Chemical and Engineering Data, vol. 58, no. 8, pp. 2154-2162. https://doi.org/10.1021/je400045d
Ghareh Bagh, Fatemeh Saadat ; Mjalli, Farouq S. ; Hashim, Mohd Ali ; Hadj-Kali, Mohamed Kamel Omar ; Alnashef, Inas M. / Solubility of sodium salts in ammonium-based deep eutectic solvents. In: Journal of Chemical and Engineering Data. 2013 ; Vol. 58, No. 8. pp. 2154-2162.
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