Abstract
In this study, the solubility of sodium chloride in 16 imidazolium-, pyrrolidinium-, pyridinium-, and ammonium-based ionic liquids at different temperatures was measured. The solubility of sodium chloride was found to increase with temperature in all of the ionic liquids studied. Both cations and anions in the ionic liquid affected solubility, but anions had more of an effect than cations. The highest measured solubility of sodium chloride was 8.96 wt % at 125 C in 1-ethyl-3-methylimidazolium dimethyl phosphate. The nonrandom two-liquid model was used to calculate the solubility of sodium chloride in some ionic liquids. The experimental and calculated values were in good agreement in many cases.
| Original language | English |
|---|---|
| Pages (from-to) | 11488-11493 |
| Number of pages | 6 |
| Journal | Industrial and Engineering Chemistry Research |
| Volume | 52 |
| Issue number | 33 |
| DOIs | |
| Publication status | Published - Aug 21 2013 |
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ASJC Scopus subject areas
- Chemical Engineering(all)
- Chemistry(all)
- Industrial and Manufacturing Engineering
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Solubility of sodium chloride in ionic liquids. / Ghareh Bagh, Fatemeh Saadat; Mjalli, Farouq S.; Hashim, Mohd Ali; Hadj-Kali, Mohamed Kamel Omar; Alnashef, Inas M.
In: Industrial and Engineering Chemistry Research, Vol. 52, No. 33, 21.08.2013, p. 11488-11493.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Solubility of sodium chloride in ionic liquids
AU - Ghareh Bagh, Fatemeh Saadat
AU - Mjalli, Farouq S.
AU - Hashim, Mohd Ali
AU - Hadj-Kali, Mohamed Kamel Omar
AU - Alnashef, Inas M.
PY - 2013/8/21
Y1 - 2013/8/21
N2 - In this study, the solubility of sodium chloride in 16 imidazolium-, pyrrolidinium-, pyridinium-, and ammonium-based ionic liquids at different temperatures was measured. The solubility of sodium chloride was found to increase with temperature in all of the ionic liquids studied. Both cations and anions in the ionic liquid affected solubility, but anions had more of an effect than cations. The highest measured solubility of sodium chloride was 8.96 wt % at 125 C in 1-ethyl-3-methylimidazolium dimethyl phosphate. The nonrandom two-liquid model was used to calculate the solubility of sodium chloride in some ionic liquids. The experimental and calculated values were in good agreement in many cases.
AB - In this study, the solubility of sodium chloride in 16 imidazolium-, pyrrolidinium-, pyridinium-, and ammonium-based ionic liquids at different temperatures was measured. The solubility of sodium chloride was found to increase with temperature in all of the ionic liquids studied. Both cations and anions in the ionic liquid affected solubility, but anions had more of an effect than cations. The highest measured solubility of sodium chloride was 8.96 wt % at 125 C in 1-ethyl-3-methylimidazolium dimethyl phosphate. The nonrandom two-liquid model was used to calculate the solubility of sodium chloride in some ionic liquids. The experimental and calculated values were in good agreement in many cases.
UR - http://www.scopus.com/inward/record.url?scp=84883171311&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84883171311&partnerID=8YFLogxK
U2 - 10.1021/ie401282y
DO - 10.1021/ie401282y
M3 - Article
AN - SCOPUS:84883171311
VL - 52
SP - 11488
EP - 11493
JO - Industrial & Engineering Chemistry Product Research and Development
JF - Industrial & Engineering Chemistry Product Research and Development
SN - 0888-5885
IS - 33
ER -