Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n

Melinda J. Duer, Muhammad S. Khan, Ashok K. Kakkar

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

Original languageEnglish
Pages (from-to)13-16
Number of pages4
JournalSolid State Nuclear Magnetic Resonance
Volume1
Issue number1
DOIs
Publication statusPublished - 1992

Fingerprint

Platinum
Electronic properties
Shielding
Tensors
shielding
platinum
Ligands
Nuclear magnetic resonance
tensors
electronic structure
solid state
nuclear magnetic resonance
ligands
electronics

Keywords

  • acetylide
  • phosphorous
  • platinum
  • polymer
  • shielding tensor

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Electronic, Optical and Magnetic Materials

Cite this

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title = "Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n",
abstract = "Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.",
keywords = "acetylide, phosphorous, platinum, polymer, shielding tensor",
author = "Duer, {Melinda J.} and Khan, {Muhammad S.} and Kakkar, {Ashok K.}",
year = "1992",
doi = "10.1016/0926-2040(92)90005-T",
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journal = "Solid State Nuclear Magnetic Resonance",
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TY - JOUR

T1 - Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n

AU - Duer, Melinda J.

AU - Khan, Muhammad S.

AU - Kakkar, Ashok K.

PY - 1992

Y1 - 1992

N2 - Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

AB - Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

KW - acetylide

KW - phosphorous

KW - platinum

KW - polymer

KW - shielding tensor

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