Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.
|Number of pages||4|
|Journal||Solid State Nuclear Magnetic Resonance|
|Publication status||Published - Feb 1992|
- shielding tensor
ASJC Scopus subject areas
- Nuclear and High Energy Physics