Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n

Melinda J. Duer*, Muhammad S. Khan, Ashok K. Kakkar

*Corresponding author for this work

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

Original languageEnglish
Pages (from-to)13-16
Number of pages4
JournalSolid State Nuclear Magnetic Resonance
Volume1
Issue number1
DOIs
Publication statusPublished - 1992

Keywords

  • acetylide
  • phosphorous
  • platinum
  • polymer
  • shielding tensor

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Electronic, Optical and Magnetic Materials

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