Self-assembled mesoporous hierarchical-like In2S3 hollow microspheres composed of nanofibers and nanosheets and their photocatalytic activity

Selvaraj Rengaraj, Selvaraj Venkataraj, Cheuk Wai Tai, Younghun Kim, Eveliina Repo, Mika Sillanpää

Research output: Contribution to journalArticle

111 Citations (Scopus)

Abstract

Novel template-free hierarchical-like In2S3 hollow microspheres were synthesized using thiosemicarbazide (NH2NHCSNH 2) as both a sulfur source and a capping ligand in a ethanol/water system. In this study, we demonstrate that several process parameters, such as the reaction time and precursor ratio, strongly influence the morphology of the final product. The In(NO3)3/thiosemicarbazide ratios were found to effectively play crucial roles in the morphologies of the hierarchical-like In2S3 hollow microsphere nanostructure. With the ratios increasing from two to four, the In2S3 crystals exhibited almost spherical morphologies. The synthesized products have been characterized by a variety of methods, including X-ray powder diffraction (XRD), Raman spectroscopy, field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy-dispersive X-ray (EDX) analysis, X-ray photoelectron spectroscopy (XPS), and ultraviolet-visible diffused reflectance spectroscopy (UV-vis DRS). XRD analysis confirmed the tetragonal structure of the In2S3 hollow microspheres. The products show complex hierarchical structures assembled from nanoscale building blocks. The morphology evolution can be realized on both outside (surface) and inside (hollow cavity) the microsphere. The surface area analysis showed that the porous In2S3 possesses a specific surface area of 108 m2/g and uniform distribution of pore sizes corresponding to the size of pores resulting from the self-assembled structures with flakes. The optical properties of In2S3 were also investigated by UV-vis DRS, which indicated that our In2S3 microsphere samples possess a band gap of ∼1.96 eV. Furthermore, the photocatalytic activity studies revealed that the synthesized In 2S3 hollow microspheres exhibit an excellent photocatalytic performance in rapidly degrading aqueous methylene blue dye solution under visible light irradiation. These results suggest that In 2S3 hollow microspheres will be an interesting candidate for photocatalytic detoxification studies under visible light radiation.

Original languageEnglish
Pages (from-to)5534-5541
Number of pages8
JournalLangmuir
Volume27
Issue number9
DOIs
Publication statusPublished - May 3 2011

Fingerprint

Nanosheets
Nanofibers
Microspheres
hollow
X ray powder diffraction
x rays
products
porosity
reflectance
Spectroscopy
flakes
methylene blue
Detoxification
Energy dispersive X ray analysis
diffraction
Methylene Blue
reaction time
spectroscopy
High resolution transmission electron microscopy
field emission

ASJC Scopus subject areas

  • Electrochemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Materials Science(all)
  • Spectroscopy

Cite this

Self-assembled mesoporous hierarchical-like In2S3 hollow microspheres composed of nanofibers and nanosheets and their photocatalytic activity. / Rengaraj, Selvaraj; Venkataraj, Selvaraj; Tai, Cheuk Wai; Kim, Younghun; Repo, Eveliina; Sillanpää, Mika.

In: Langmuir, Vol. 27, No. 9, 03.05.2011, p. 5534-5541.

Research output: Contribution to journalArticle

Rengaraj, Selvaraj ; Venkataraj, Selvaraj ; Tai, Cheuk Wai ; Kim, Younghun ; Repo, Eveliina ; Sillanpää, Mika. / Self-assembled mesoporous hierarchical-like In2S3 hollow microspheres composed of nanofibers and nanosheets and their photocatalytic activity. In: Langmuir. 2011 ; Vol. 27, No. 9. pp. 5534-5541.
@article{d172fbe365184620a2670d80b4967525,
title = "Self-assembled mesoporous hierarchical-like In2S3 hollow microspheres composed of nanofibers and nanosheets and their photocatalytic activity",
abstract = "Novel template-free hierarchical-like In2S3 hollow microspheres were synthesized using thiosemicarbazide (NH2NHCSNH 2) as both a sulfur source and a capping ligand in a ethanol/water system. In this study, we demonstrate that several process parameters, such as the reaction time and precursor ratio, strongly influence the morphology of the final product. The In(NO3)3/thiosemicarbazide ratios were found to effectively play crucial roles in the morphologies of the hierarchical-like In2S3 hollow microsphere nanostructure. With the ratios increasing from two to four, the In2S3 crystals exhibited almost spherical morphologies. The synthesized products have been characterized by a variety of methods, including X-ray powder diffraction (XRD), Raman spectroscopy, field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy-dispersive X-ray (EDX) analysis, X-ray photoelectron spectroscopy (XPS), and ultraviolet-visible diffused reflectance spectroscopy (UV-vis DRS). XRD analysis confirmed the tetragonal structure of the In2S3 hollow microspheres. The products show complex hierarchical structures assembled from nanoscale building blocks. The morphology evolution can be realized on both outside (surface) and inside (hollow cavity) the microsphere. The surface area analysis showed that the porous In2S3 possesses a specific surface area of 108 m2/g and uniform distribution of pore sizes corresponding to the size of pores resulting from the self-assembled structures with flakes. The optical properties of In2S3 were also investigated by UV-vis DRS, which indicated that our In2S3 microsphere samples possess a band gap of ∼1.96 eV. Furthermore, the photocatalytic activity studies revealed that the synthesized In 2S3 hollow microspheres exhibit an excellent photocatalytic performance in rapidly degrading aqueous methylene blue dye solution under visible light irradiation. These results suggest that In 2S3 hollow microspheres will be an interesting candidate for photocatalytic detoxification studies under visible light radiation.",
author = "Selvaraj Rengaraj and Selvaraj Venkataraj and Tai, {Cheuk Wai} and Younghun Kim and Eveliina Repo and Mika Sillanp{\"a}{\"a}",
year = "2011",
month = "5",
day = "3",
doi = "10.1021/la104780d",
language = "English",
volume = "27",
pages = "5534--5541",
journal = "Langmuir",
issn = "0743-7463",
publisher = "American Chemical Society",
number = "9",

}

TY - JOUR

T1 - Self-assembled mesoporous hierarchical-like In2S3 hollow microspheres composed of nanofibers and nanosheets and their photocatalytic activity

AU - Rengaraj, Selvaraj

AU - Venkataraj, Selvaraj

AU - Tai, Cheuk Wai

AU - Kim, Younghun

AU - Repo, Eveliina

AU - Sillanpää, Mika

PY - 2011/5/3

Y1 - 2011/5/3

N2 - Novel template-free hierarchical-like In2S3 hollow microspheres were synthesized using thiosemicarbazide (NH2NHCSNH 2) as both a sulfur source and a capping ligand in a ethanol/water system. In this study, we demonstrate that several process parameters, such as the reaction time and precursor ratio, strongly influence the morphology of the final product. The In(NO3)3/thiosemicarbazide ratios were found to effectively play crucial roles in the morphologies of the hierarchical-like In2S3 hollow microsphere nanostructure. With the ratios increasing from two to four, the In2S3 crystals exhibited almost spherical morphologies. The synthesized products have been characterized by a variety of methods, including X-ray powder diffraction (XRD), Raman spectroscopy, field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy-dispersive X-ray (EDX) analysis, X-ray photoelectron spectroscopy (XPS), and ultraviolet-visible diffused reflectance spectroscopy (UV-vis DRS). XRD analysis confirmed the tetragonal structure of the In2S3 hollow microspheres. The products show complex hierarchical structures assembled from nanoscale building blocks. The morphology evolution can be realized on both outside (surface) and inside (hollow cavity) the microsphere. The surface area analysis showed that the porous In2S3 possesses a specific surface area of 108 m2/g and uniform distribution of pore sizes corresponding to the size of pores resulting from the self-assembled structures with flakes. The optical properties of In2S3 were also investigated by UV-vis DRS, which indicated that our In2S3 microsphere samples possess a band gap of ∼1.96 eV. Furthermore, the photocatalytic activity studies revealed that the synthesized In 2S3 hollow microspheres exhibit an excellent photocatalytic performance in rapidly degrading aqueous methylene blue dye solution under visible light irradiation. These results suggest that In 2S3 hollow microspheres will be an interesting candidate for photocatalytic detoxification studies under visible light radiation.

AB - Novel template-free hierarchical-like In2S3 hollow microspheres were synthesized using thiosemicarbazide (NH2NHCSNH 2) as both a sulfur source and a capping ligand in a ethanol/water system. In this study, we demonstrate that several process parameters, such as the reaction time and precursor ratio, strongly influence the morphology of the final product. The In(NO3)3/thiosemicarbazide ratios were found to effectively play crucial roles in the morphologies of the hierarchical-like In2S3 hollow microsphere nanostructure. With the ratios increasing from two to four, the In2S3 crystals exhibited almost spherical morphologies. The synthesized products have been characterized by a variety of methods, including X-ray powder diffraction (XRD), Raman spectroscopy, field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy-dispersive X-ray (EDX) analysis, X-ray photoelectron spectroscopy (XPS), and ultraviolet-visible diffused reflectance spectroscopy (UV-vis DRS). XRD analysis confirmed the tetragonal structure of the In2S3 hollow microspheres. The products show complex hierarchical structures assembled from nanoscale building blocks. The morphology evolution can be realized on both outside (surface) and inside (hollow cavity) the microsphere. The surface area analysis showed that the porous In2S3 possesses a specific surface area of 108 m2/g and uniform distribution of pore sizes corresponding to the size of pores resulting from the self-assembled structures with flakes. The optical properties of In2S3 were also investigated by UV-vis DRS, which indicated that our In2S3 microsphere samples possess a band gap of ∼1.96 eV. Furthermore, the photocatalytic activity studies revealed that the synthesized In 2S3 hollow microspheres exhibit an excellent photocatalytic performance in rapidly degrading aqueous methylene blue dye solution under visible light irradiation. These results suggest that In 2S3 hollow microspheres will be an interesting candidate for photocatalytic detoxification studies under visible light radiation.

UR - http://www.scopus.com/inward/record.url?scp=79955369314&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79955369314&partnerID=8YFLogxK

U2 - 10.1021/la104780d

DO - 10.1021/la104780d

M3 - Article

VL - 27

SP - 5534

EP - 5541

JO - Langmuir

JF - Langmuir

SN - 0743-7463

IS - 9

ER -