TY - JOUR
T1 - Self-Assembled Graphene Hydrogel Composites for Selective Dye Removal
AU - Al Subhi, Azza
AU - Valizadeh Kiamahalleh, Mohammad
AU - Firouzi, Maryam
AU - Yousefi, Fereshteh
AU - Kyaw, Htet Htet
AU - Al Abri, Mohammed
AU - Firouzi, Amin
AU - Valizadeh Kiamahalleh, Meisam
N1 - Funding Information:
The authors gratefully acknowledge the support of The Research Council (TRC) Oman through FURAP funding 2018 and International Maritime College Oman (IMCO) for a college research grant (CRG2018). The authors also thank The School of Chemical Engineering at The University of Adelaide and The Nanotechnology Research Center at Sultan Qaboos University for supporting this work in material preparation and characterizations, respectively.
Funding Information:
The authors gratefully acknowledge the support of The Research Council (TRC) Oman through FURAP funding 2018 and International Maritime College Oman (IMCO) for a college research grant (CRG2018). The authors also thank The School of Chemical Engineering at The University of Adelaide and The Nanotechnology Research Center at Sultan Qaboos University for supporting this work in material preparation and characterizations, respectively.
Publisher Copyright:
© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2020/9/1
Y1 - 2020/9/1
N2 - Graphene-based hydrogels are known as promising amphiphilic agents for water uptake and selective organic contaminant removal. However, it is a challenge to prevent graphene sheet restacking during the gelation as this factor significantly influences the adsorption behavior of organic contaminant. A porous reduced graphene oxide-starch hydrogel (rGOSH) with enhanced pore size is produced by a simple one-step method through starch-directed self-assembly of graphene sheets. This hydrogel demonstrated to be a promising candidate for the selective removal of organic dye molecules, where positive and neutral dyes are adsorbed, and the negative one is repelled. In particular, the hydrogel prepared with incorporation of starch between the graphene sheets, adsorbs positively charged dye ≈75% more than reduced graphene oxide hydrogel, due to better diffusion into larger pore size and strong electrostatic interaction with negatively charged oxygen groups. Furthermore, the Langmuir isotherm model and kinetic studies for dyes adsorption onto rGOSH reveal that the adsorption mechanisms are dominantly chemisorption within the porous hydrogel structure since the experimental data can be well fitted to the pseudo-second-order dynamic equation with the highest adsorption capacity (1106.950 µg g−1) and kinetic (1.957E-05 g µg−1 min−0.5) toward the positively charged dye.
AB - Graphene-based hydrogels are known as promising amphiphilic agents for water uptake and selective organic contaminant removal. However, it is a challenge to prevent graphene sheet restacking during the gelation as this factor significantly influences the adsorption behavior of organic contaminant. A porous reduced graphene oxide-starch hydrogel (rGOSH) with enhanced pore size is produced by a simple one-step method through starch-directed self-assembly of graphene sheets. This hydrogel demonstrated to be a promising candidate for the selective removal of organic dye molecules, where positive and neutral dyes are adsorbed, and the negative one is repelled. In particular, the hydrogel prepared with incorporation of starch between the graphene sheets, adsorbs positively charged dye ≈75% more than reduced graphene oxide hydrogel, due to better diffusion into larger pore size and strong electrostatic interaction with negatively charged oxygen groups. Furthermore, the Langmuir isotherm model and kinetic studies for dyes adsorption onto rGOSH reveal that the adsorption mechanisms are dominantly chemisorption within the porous hydrogel structure since the experimental data can be well fitted to the pseudo-second-order dynamic equation with the highest adsorption capacity (1106.950 µg g−1) and kinetic (1.957E-05 g µg−1 min−0.5) toward the positively charged dye.
KW - dyes
KW - hydrogels
KW - reduced graphene oxide
KW - selective adsorption
KW - starch
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U2 - 10.1002/adsu.202000055
DO - 10.1002/adsu.202000055
M3 - Article
AN - SCOPUS:85087207906
SN - 2366-7486
VL - 4
JO - Advanced Sustainable Systems
JF - Advanced Sustainable Systems
IS - 9
M1 - 2000055
ER -