Segregation and immiscibility in liquid binary alloys

R. N. Singh, F. Sommer

Research output: Contribution to journalArticle

164 Citations (Scopus)

Abstract

An overview of the thermophysical properties of segregating and demixing liquid binary alloys is presented encompassing the simple approaches that are commonly used by physicists, chemists and metallurgists in general. The various experimental and theoretical information available for such systems are put together to establish a respectable understanding between the experimental results, theoretical approaches and the empirical models. The key to understanding is the deviation that the properties exhibit from Raoult's law and the marked change in the liquid phase as a function of composition, temperature and pressure. The characteristic behaviour is ascribed to an outcome of the interplay of the energetic and structural re-adjustment of the constituent elements on mixing. After summarizing the experimental technique and some results, a comprehensive microscopic approach, based on statistical, electronic and hard sphere-like theory, is undertaken to further the understanding of the origin of the intriguing processes that are associated with the immiscible and phase-separating liquid alloys. We conclude by providing a brief account of the kinetic aspects of phase separation with some intended industrial applications.

Original languageEnglish
Pages (from-to)57-150
Number of pages94
JournalReports on Progress in Physics
Volume60
Issue number1
DOIs
Publication statusPublished - 1997

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liquid alloys
binary alloys
solubility
Raoult law
thermophysical properties
liquid phases
adjusting
deviation
Pressure
Temperature
kinetics
electronics
temperature

ASJC Scopus subject areas

  • Medicine(all)
  • Physics and Astronomy(all)

Cite this

Segregation and immiscibility in liquid binary alloys. / Singh, R. N.; Sommer, F.

In: Reports on Progress in Physics, Vol. 60, No. 1, 1997, p. 57-150.

Research output: Contribution to journalArticle

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