Abstract
The synthetic utility of bis(trimethylstannyl)alkynyls in the preparation of Group 8 metal (Fe2+, Ru2+, Os2+) σ-acetylide monomeric, M(DEPE)2(CCC6H5)2 (M Fe2+, Ru2+; DEPE = 1,2-bis(diethylphosphino)ethane), Ru(DPPE)2 (CCC6H5)2 (DPPE = 1,2-bis(diphenylphosphino)ethane), Os(DPPM)2(CCC6H5) 2 (DPPM = 1,2-bis(diphenylphosphino)methane) and polymeric, [M(DEPE)2CCRCC]n (M Fe2+, Ru2+), [Os(DPPM)2CCRCC-]n (R = p-C6H4- C6H4-p, p-C6H4, p-C6H2(CH3)2) complexes is demonstrated. The linear arrangement of the acetylenic units around octahedral metal centres is confirmed by a single crystal X-ray structure determination of the model complex trans-[Ru(DPPE) 2(CCC6H5)2].
| Original language | English |
|---|---|
| Pages (from-to) | 265-270 |
| Number of pages | 6 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 462 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Dec 14 1993 |
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ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Rigid rod σ-acetylide complexes of iron, ruthenium and osmium. / Atherton, Zeno; Faulkner, Charlotte W.; Ingham, Scott L.; Kakkar, Ashok K.; Khan, Muhammad S.; Lewis, Jack; Long, Nicholas J.; Raithby, Paul R.
In: Journal of Organometallic Chemistry, Vol. 462, No. 1-2, 14.12.1993, p. 265-270.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Rigid rod σ-acetylide complexes of iron, ruthenium and osmium
AU - Atherton, Zeno
AU - Faulkner, Charlotte W.
AU - Ingham, Scott L.
AU - Kakkar, Ashok K.
AU - Khan, Muhammad S.
AU - Lewis, Jack
AU - Long, Nicholas J.
AU - Raithby, Paul R.
PY - 1993/12/14
Y1 - 1993/12/14
N2 - The synthetic utility of bis(trimethylstannyl)alkynyls in the preparation of Group 8 metal (Fe2+, Ru2+, Os2+) σ-acetylide monomeric, M(DEPE)2(CCC6H5)2 (M Fe2+, Ru2+; DEPE = 1,2-bis(diethylphosphino)ethane), Ru(DPPE)2 (CCC6H5)2 (DPPE = 1,2-bis(diphenylphosphino)ethane), Os(DPPM)2(CCC6H5) 2 (DPPM = 1,2-bis(diphenylphosphino)methane) and polymeric, [M(DEPE)2CCRCC]n (M Fe2+, Ru2+), [Os(DPPM)2CCRCC-]n (R = p-C6H4- C6H4-p, p-C6H4, p-C6H2(CH3)2) complexes is demonstrated. The linear arrangement of the acetylenic units around octahedral metal centres is confirmed by a single crystal X-ray structure determination of the model complex trans-[Ru(DPPE) 2(CCC6H5)2].
AB - The synthetic utility of bis(trimethylstannyl)alkynyls in the preparation of Group 8 metal (Fe2+, Ru2+, Os2+) σ-acetylide monomeric, M(DEPE)2(CCC6H5)2 (M Fe2+, Ru2+; DEPE = 1,2-bis(diethylphosphino)ethane), Ru(DPPE)2 (CCC6H5)2 (DPPE = 1,2-bis(diphenylphosphino)ethane), Os(DPPM)2(CCC6H5) 2 (DPPM = 1,2-bis(diphenylphosphino)methane) and polymeric, [M(DEPE)2CCRCC]n (M Fe2+, Ru2+), [Os(DPPM)2CCRCC-]n (R = p-C6H4- C6H4-p, p-C6H4, p-C6H2(CH3)2) complexes is demonstrated. The linear arrangement of the acetylenic units around octahedral metal centres is confirmed by a single crystal X-ray structure determination of the model complex trans-[Ru(DPPE) 2(CCC6H5)2].
UR - http://www.scopus.com/inward/record.url?scp=0000436664&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000436664&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(93)83367-5
DO - 10.1016/0022-328X(93)83367-5
M3 - Article
AN - SCOPUS:0000436664
VL - 462
SP - 265
EP - 270
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1-2
ER -