Rigid rod σ-acetylide complexes of iron, ruthenium and osmium

Zeno Atherton, Charlotte W. Faulkner, Scott L. Ingham, Ashok K. Kakkar, Muhammad S. Khan, Jack Lewis, Nicholas J. Long, Paul R. Raithby

Research output: Contribution to journalArticle

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Abstract

The synthetic utility of bis(trimethylstannyl)alkynyls in the preparation of Group 8 metal (Fe2+, Ru2+, Os2+) σ-acetylide monomeric, M(DEPE)2(CCC6H5)2 (M Fe2+, Ru2+; DEPE = 1,2-bis(diethylphosphino)ethane), Ru(DPPE)2 (CCC6H5)2 (DPPE = 1,2-bis(diphenylphosphino)ethane), Os(DPPM)2(CCC6H5) 2 (DPPM = 1,2-bis(diphenylphosphino)methane) and polymeric, [M(DEPE)2CCRCC]n (M Fe2+, Ru2+), [Os(DPPM)2CCRCC-]n (R = p-C6H4- C6H4-p, p-C6H4, p-C6H2(CH3)2) complexes is demonstrated. The linear arrangement of the acetylenic units around octahedral metal centres is confirmed by a single crystal X-ray structure determination of the model complex trans-[Ru(DPPE) 2(CCC6H5)2].

Original languageEnglish
Pages (from-to)265-270
Number of pages6
JournalJournal of Organometallic Chemistry
Volume462
Issue number1-2
DOIs
Publication statusPublished - Dec 14 1993

Fingerprint

Osmium
Ruthenium
osmium
Ethane
ethane
ruthenium
rods
Iron
iron
Metals
metals
Methane
methane
Single crystals
X rays
preparation
single crystals
X-Rays
x rays
1,2-dipalmitoyl-3-phosphatidylethanolamine

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Atherton, Z., Faulkner, C. W., Ingham, S. L., Kakkar, A. K., Khan, M. S., Lewis, J., ... Raithby, P. R. (1993). Rigid rod σ-acetylide complexes of iron, ruthenium and osmium. Journal of Organometallic Chemistry, 462(1-2), 265-270. https://doi.org/10.1016/0022-328X(93)83367-5

Rigid rod σ-acetylide complexes of iron, ruthenium and osmium. / Atherton, Zeno; Faulkner, Charlotte W.; Ingham, Scott L.; Kakkar, Ashok K.; Khan, Muhammad S.; Lewis, Jack; Long, Nicholas J.; Raithby, Paul R.

In: Journal of Organometallic Chemistry, Vol. 462, No. 1-2, 14.12.1993, p. 265-270.

Research output: Contribution to journalArticle

Atherton, Z, Faulkner, CW, Ingham, SL, Kakkar, AK, Khan, MS, Lewis, J, Long, NJ & Raithby, PR 1993, 'Rigid rod σ-acetylide complexes of iron, ruthenium and osmium', Journal of Organometallic Chemistry, vol. 462, no. 1-2, pp. 265-270. https://doi.org/10.1016/0022-328X(93)83367-5
Atherton, Zeno ; Faulkner, Charlotte W. ; Ingham, Scott L. ; Kakkar, Ashok K. ; Khan, Muhammad S. ; Lewis, Jack ; Long, Nicholas J. ; Raithby, Paul R. / Rigid rod σ-acetylide complexes of iron, ruthenium and osmium. In: Journal of Organometallic Chemistry. 1993 ; Vol. 462, No. 1-2. pp. 265-270.
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