Removal of Zn2+ and SO4 2− from aqueous solutions on acidic and chelating dehydrated carbon

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Abstract

The agricultural waste, date palm leaflets, was carbonized chemically using sulfuric acid treatment. Produced dehydrated carbon (DC) was subjected to surface functionalization using ethylene diamine producing chelating dehydrated carbon (CDC). In the process, ∼80 % of the carboxylic content on DC was converted to amide successfully. DC acts as a cation exchanger because of the high content of carboxylic groups on its surface showing acidic nature. However, CDC possesses amine and amide groups showing basic nature. Both amine and amide groups are capable of chelating Zn2+ at high pH; however, at low pH, the amine group becomes protonated acting as anion exchanger. Sorption of Zn2+ and SO4 2− was investigated in terms of contact time, initial pH, concentration, and carbon reuse. Zn2+ shows maximum sorption at initial pH 5; however, maximum sorption of SO4 2− takes place at initial pH 2. Kinetic and equilibrium studies were carried out at initial 5 and 2 for Zn2+and SO4 2−, respectively. Sorption kinetics data follow well the pseudo second-order model. The equilibrium sorption data follow the Langmuir isotherm more than the Freundlich isotherm. CDC shows better sorption performance for Zn2+ and SO4 2− than DC. DC and CDC show combined equimolar removal of both Zn2+ and SO4 2− at initial pH 2.3 and 2.6, respectively, with efficient recycle properties. Combined removal of Zn2+ and SO4 2− from spiked municipal wastewater shows less uptake on both carbons than from deionized water.

Original languageEnglish
Pages (from-to)1-12
Number of pages12
JournalEnvironmental Science and Pollution Research
DOIs
Publication statusAccepted/In press - May 7 2016

Fingerprint

Chelation
Carbon
aqueous solution
carbon
Sorption
sorption
Amides
Amines
Ion exchangers
Isotherms
isotherm
removal
kinetics
Agricultural wastes
Kinetics
Diamines
Deionized water
Waste Water
Sulfuric acid
sulfuric acid

Keywords

  • Carbon
  • Chelating
  • Dehydrated
  • SO
  • Sorption
  • Zn

ASJC Scopus subject areas

  • Environmental Chemistry
  • Health, Toxicology and Mutagenesis
  • Pollution

Cite this

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title = "Removal of Zn2+ and SO4 2− from aqueous solutions on acidic and chelating dehydrated carbon",
abstract = "The agricultural waste, date palm leaflets, was carbonized chemically using sulfuric acid treatment. Produced dehydrated carbon (DC) was subjected to surface functionalization using ethylene diamine producing chelating dehydrated carbon (CDC). In the process, ∼80 {\%} of the carboxylic content on DC was converted to amide successfully. DC acts as a cation exchanger because of the high content of carboxylic groups on its surface showing acidic nature. However, CDC possesses amine and amide groups showing basic nature. Both amine and amide groups are capable of chelating Zn2+ at high pH; however, at low pH, the amine group becomes protonated acting as anion exchanger. Sorption of Zn2+ and SO4 2− was investigated in terms of contact time, initial pH, concentration, and carbon reuse. Zn2+ shows maximum sorption at initial pH 5; however, maximum sorption of SO4 2− takes place at initial pH 2. Kinetic and equilibrium studies were carried out at initial 5 and 2 for Zn2+and SO4 2−, respectively. Sorption kinetics data follow well the pseudo second-order model. The equilibrium sorption data follow the Langmuir isotherm more than the Freundlich isotherm. CDC shows better sorption performance for Zn2+ and SO4 2− than DC. DC and CDC show combined equimolar removal of both Zn2+ and SO4 2− at initial pH 2.3 and 2.6, respectively, with efficient recycle properties. Combined removal of Zn2+ and SO4 2− from spiked municipal wastewater shows less uptake on both carbons than from deionized water.",
keywords = "Carbon, Chelating, Dehydrated, SO, Sorption, Zn",
author = "El-Shafey, {El Said I} and Al-Lawati, {Haider A J} and Saleh Al-Busafi and Badriya Al-Shiraiqi",
year = "2016",
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T1 - Removal of Zn2+ and SO4 2− from aqueous solutions on acidic and chelating dehydrated carbon

AU - El-Shafey, El Said I

AU - Al-Lawati, Haider A J

AU - Al-Busafi, Saleh

AU - Al-Shiraiqi, Badriya

PY - 2016/5/7

Y1 - 2016/5/7

N2 - The agricultural waste, date palm leaflets, was carbonized chemically using sulfuric acid treatment. Produced dehydrated carbon (DC) was subjected to surface functionalization using ethylene diamine producing chelating dehydrated carbon (CDC). In the process, ∼80 % of the carboxylic content on DC was converted to amide successfully. DC acts as a cation exchanger because of the high content of carboxylic groups on its surface showing acidic nature. However, CDC possesses amine and amide groups showing basic nature. Both amine and amide groups are capable of chelating Zn2+ at high pH; however, at low pH, the amine group becomes protonated acting as anion exchanger. Sorption of Zn2+ and SO4 2− was investigated in terms of contact time, initial pH, concentration, and carbon reuse. Zn2+ shows maximum sorption at initial pH 5; however, maximum sorption of SO4 2− takes place at initial pH 2. Kinetic and equilibrium studies were carried out at initial 5 and 2 for Zn2+and SO4 2−, respectively. Sorption kinetics data follow well the pseudo second-order model. The equilibrium sorption data follow the Langmuir isotherm more than the Freundlich isotherm. CDC shows better sorption performance for Zn2+ and SO4 2− than DC. DC and CDC show combined equimolar removal of both Zn2+ and SO4 2− at initial pH 2.3 and 2.6, respectively, with efficient recycle properties. Combined removal of Zn2+ and SO4 2− from spiked municipal wastewater shows less uptake on both carbons than from deionized water.

AB - The agricultural waste, date palm leaflets, was carbonized chemically using sulfuric acid treatment. Produced dehydrated carbon (DC) was subjected to surface functionalization using ethylene diamine producing chelating dehydrated carbon (CDC). In the process, ∼80 % of the carboxylic content on DC was converted to amide successfully. DC acts as a cation exchanger because of the high content of carboxylic groups on its surface showing acidic nature. However, CDC possesses amine and amide groups showing basic nature. Both amine and amide groups are capable of chelating Zn2+ at high pH; however, at low pH, the amine group becomes protonated acting as anion exchanger. Sorption of Zn2+ and SO4 2− was investigated in terms of contact time, initial pH, concentration, and carbon reuse. Zn2+ shows maximum sorption at initial pH 5; however, maximum sorption of SO4 2− takes place at initial pH 2. Kinetic and equilibrium studies were carried out at initial 5 and 2 for Zn2+and SO4 2−, respectively. Sorption kinetics data follow well the pseudo second-order model. The equilibrium sorption data follow the Langmuir isotherm more than the Freundlich isotherm. CDC shows better sorption performance for Zn2+ and SO4 2− than DC. DC and CDC show combined equimolar removal of both Zn2+ and SO4 2− at initial pH 2.3 and 2.6, respectively, with efficient recycle properties. Combined removal of Zn2+ and SO4 2− from spiked municipal wastewater shows less uptake on both carbons than from deionized water.

KW - Carbon

KW - Chelating

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KW - SO

KW - Sorption

KW - Zn

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