Removal of Cu2+ and Ag+ from aqueous solution on a chemically-carbonized sorbent from date palm leaflets

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Abstract

A chemically-carbonized sorbent was prepared from date palm leaflets by sulphuric acid treatment at 170°C. Carbonization took place via the dehydration effect of the hot sulphuric acid producing a carbon with reduction property. Sorption of Cu2+ and Ag+ from aqueous solution was investigated in terms of pH, contact time, metal concentration and temperature. A peculiar behaviour was found for the sorption of the two metals on the produced carbon. Sorption of Cu2+ was fast, reaching equilibrium within ∼2 h, whilst Ag+ sorption was slow and required ∼60 h to reach equilibrium. Activation energy (Ea) for Cu2+ sorption was ∼16.1 kJ/mol indicating a diffusion-controlled ion exchange process; however, Ea for Ag+ sorption was ∼44.3 kJ/mol indicating a chemically controlled process. Equilibrium sorption data were tested for the Langmuir and Freundlich equations. Sorption capacity appears to be much higher for Ag+ than for Cu2+ with increased uptake, for both metals, when increasing the temperature (25-45°C). Ag+ was reduced to elemental silver on the sorbent surface and this was confirmed using scanning electron microscopy and x-ray powder diffraction; however, no reduction processes were involved in Cu 2+ sorption. This paper discusses the sorption mechanism.

Original languageEnglish
Pages (from-to)395-406
Number of pages12
JournalEnvironmental Technology (United Kingdom)
Volume34
Issue number3
DOIs
Publication statusPublished - Feb 1 2013

Fingerprint

Sorbents
Sorption
aqueous solution
sorption
Metals
sulfuric acid
metal
Carbon
removal
Acids
carbon
Carbonization
Dehydration
Silver
dehydration
activation energy
diffraction
silver
ion exchange
Ion exchange

Keywords

  • Ag
  • carbon
  • Cu
  • reduction
  • sorption

ASJC Scopus subject areas

  • Environmental Chemistry
  • Waste Management and Disposal
  • Water Science and Technology

Cite this

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abstract = "A chemically-carbonized sorbent was prepared from date palm leaflets by sulphuric acid treatment at 170°C. Carbonization took place via the dehydration effect of the hot sulphuric acid producing a carbon with reduction property. Sorption of Cu2+ and Ag+ from aqueous solution was investigated in terms of pH, contact time, metal concentration and temperature. A peculiar behaviour was found for the sorption of the two metals on the produced carbon. Sorption of Cu2+ was fast, reaching equilibrium within ∼2 h, whilst Ag+ sorption was slow and required ∼60 h to reach equilibrium. Activation energy (Ea) for Cu2+ sorption was ∼16.1 kJ/mol indicating a diffusion-controlled ion exchange process; however, Ea for Ag+ sorption was ∼44.3 kJ/mol indicating a chemically controlled process. Equilibrium sorption data were tested for the Langmuir and Freundlich equations. Sorption capacity appears to be much higher for Ag+ than for Cu2+ with increased uptake, for both metals, when increasing the temperature (25-45°C). Ag+ was reduced to elemental silver on the sorbent surface and this was confirmed using scanning electron microscopy and x-ray powder diffraction; however, no reduction processes were involved in Cu 2+ sorption. This paper discusses the sorption mechanism.",
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N2 - A chemically-carbonized sorbent was prepared from date palm leaflets by sulphuric acid treatment at 170°C. Carbonization took place via the dehydration effect of the hot sulphuric acid producing a carbon with reduction property. Sorption of Cu2+ and Ag+ from aqueous solution was investigated in terms of pH, contact time, metal concentration and temperature. A peculiar behaviour was found for the sorption of the two metals on the produced carbon. Sorption of Cu2+ was fast, reaching equilibrium within ∼2 h, whilst Ag+ sorption was slow and required ∼60 h to reach equilibrium. Activation energy (Ea) for Cu2+ sorption was ∼16.1 kJ/mol indicating a diffusion-controlled ion exchange process; however, Ea for Ag+ sorption was ∼44.3 kJ/mol indicating a chemically controlled process. Equilibrium sorption data were tested for the Langmuir and Freundlich equations. Sorption capacity appears to be much higher for Ag+ than for Cu2+ with increased uptake, for both metals, when increasing the temperature (25-45°C). Ag+ was reduced to elemental silver on the sorbent surface and this was confirmed using scanning electron microscopy and x-ray powder diffraction; however, no reduction processes were involved in Cu 2+ sorption. This paper discusses the sorption mechanism.

AB - A chemically-carbonized sorbent was prepared from date palm leaflets by sulphuric acid treatment at 170°C. Carbonization took place via the dehydration effect of the hot sulphuric acid producing a carbon with reduction property. Sorption of Cu2+ and Ag+ from aqueous solution was investigated in terms of pH, contact time, metal concentration and temperature. A peculiar behaviour was found for the sorption of the two metals on the produced carbon. Sorption of Cu2+ was fast, reaching equilibrium within ∼2 h, whilst Ag+ sorption was slow and required ∼60 h to reach equilibrium. Activation energy (Ea) for Cu2+ sorption was ∼16.1 kJ/mol indicating a diffusion-controlled ion exchange process; however, Ea for Ag+ sorption was ∼44.3 kJ/mol indicating a chemically controlled process. Equilibrium sorption data were tested for the Langmuir and Freundlich equations. Sorption capacity appears to be much higher for Ag+ than for Cu2+ with increased uptake, for both metals, when increasing the temperature (25-45°C). Ag+ was reduced to elemental silver on the sorbent surface and this was confirmed using scanning electron microscopy and x-ray powder diffraction; however, no reduction processes were involved in Cu 2+ sorption. This paper discusses the sorption mechanism.

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