Recent advances in the application of group-10 transition metal based catalysts in C-H activation and functionalization

Muhammad S. Khan, Ashanul Haque, Mohammed K. Al-Suti, Paul R. Raithby

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

The importance of C-H bond activation in a simple molecule to form a molecule with enhanced functionality can be easily understood from a study of biological processes at a molecular level where, for example, a specific enzyme selectively activates a chemically inert C-H bond and functionalizes it to a useful product. This strategy is now being used for large scale industrial processes and has both social and environmental benefits. C-H bond functionalization is also of major importance in catalysis because of the possibility of constructing complex structural motifs from relatively simple precursors. However, functionalization of a chemically inert C-H bond needs specific catalysts or reaction conditions that can selectively activate a particular C-H bond, leaving others intact. To achieve this target, various metal catalyzed or mediated reactions have been employed. Keeping the growing importance of this emerging field in mind, we now present recent advances in the field of C-H activation and functionalization using group 10 transition metal catalysts. Attempts have also been made to discuss the future of group 10 transition metals in catalysis.

Original languageEnglish
Article number18974
Pages (from-to)114-133
Number of pages20
JournalJournal of Organometallic Chemistry
Volume793
DOIs
Publication statusPublished - Sep 15 2015

Fingerprint

Catalysis
catalysis
Transition metals
Metals
Chemical activation
transition metals
activation
catalysts
Catalysts
Molecules
Biological Phenomena
enzymes
molecules
emerging
Enzymes
products
metals

Keywords

  • C-H activation
  • Functionalization
  • Group 10 metal-based catalyst

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Biochemistry

Cite this

Recent advances in the application of group-10 transition metal based catalysts in C-H activation and functionalization. / Khan, Muhammad S.; Haque, Ashanul; Al-Suti, Mohammed K.; Raithby, Paul R.

In: Journal of Organometallic Chemistry, Vol. 793, 18974, 15.09.2015, p. 114-133.

Research output: Contribution to journalArticle

@article{54e42879d2eb45f893696837ea54dbb4,
title = "Recent advances in the application of group-10 transition metal based catalysts in C-H activation and functionalization",
abstract = "The importance of C-H bond activation in a simple molecule to form a molecule with enhanced functionality can be easily understood from a study of biological processes at a molecular level where, for example, a specific enzyme selectively activates a chemically inert C-H bond and functionalizes it to a useful product. This strategy is now being used for large scale industrial processes and has both social and environmental benefits. C-H bond functionalization is also of major importance in catalysis because of the possibility of constructing complex structural motifs from relatively simple precursors. However, functionalization of a chemically inert C-H bond needs specific catalysts or reaction conditions that can selectively activate a particular C-H bond, leaving others intact. To achieve this target, various metal catalyzed or mediated reactions have been employed. Keeping the growing importance of this emerging field in mind, we now present recent advances in the field of C-H activation and functionalization using group 10 transition metal catalysts. Attempts have also been made to discuss the future of group 10 transition metals in catalysis.",
keywords = "C-H activation, Functionalization, Group 10 metal-based catalyst",
author = "Khan, {Muhammad S.} and Ashanul Haque and Al-Suti, {Mohammed K.} and Raithby, {Paul R.}",
year = "2015",
month = "9",
day = "15",
doi = "10.1016/j.jorganchem.2015.03.023",
language = "English",
volume = "793",
pages = "114--133",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",

}

TY - JOUR

T1 - Recent advances in the application of group-10 transition metal based catalysts in C-H activation and functionalization

AU - Khan, Muhammad S.

AU - Haque, Ashanul

AU - Al-Suti, Mohammed K.

AU - Raithby, Paul R.

PY - 2015/9/15

Y1 - 2015/9/15

N2 - The importance of C-H bond activation in a simple molecule to form a molecule with enhanced functionality can be easily understood from a study of biological processes at a molecular level where, for example, a specific enzyme selectively activates a chemically inert C-H bond and functionalizes it to a useful product. This strategy is now being used for large scale industrial processes and has both social and environmental benefits. C-H bond functionalization is also of major importance in catalysis because of the possibility of constructing complex structural motifs from relatively simple precursors. However, functionalization of a chemically inert C-H bond needs specific catalysts or reaction conditions that can selectively activate a particular C-H bond, leaving others intact. To achieve this target, various metal catalyzed or mediated reactions have been employed. Keeping the growing importance of this emerging field in mind, we now present recent advances in the field of C-H activation and functionalization using group 10 transition metal catalysts. Attempts have also been made to discuss the future of group 10 transition metals in catalysis.

AB - The importance of C-H bond activation in a simple molecule to form a molecule with enhanced functionality can be easily understood from a study of biological processes at a molecular level where, for example, a specific enzyme selectively activates a chemically inert C-H bond and functionalizes it to a useful product. This strategy is now being used for large scale industrial processes and has both social and environmental benefits. C-H bond functionalization is also of major importance in catalysis because of the possibility of constructing complex structural motifs from relatively simple precursors. However, functionalization of a chemically inert C-H bond needs specific catalysts or reaction conditions that can selectively activate a particular C-H bond, leaving others intact. To achieve this target, various metal catalyzed or mediated reactions have been employed. Keeping the growing importance of this emerging field in mind, we now present recent advances in the field of C-H activation and functionalization using group 10 transition metal catalysts. Attempts have also been made to discuss the future of group 10 transition metals in catalysis.

KW - C-H activation

KW - Functionalization

KW - Group 10 metal-based catalyst

UR - http://www.scopus.com/inward/record.url?scp=84939568800&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84939568800&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2015.03.023

DO - 10.1016/j.jorganchem.2015.03.023

M3 - Article

AN - SCOPUS:84939568800

VL - 793

SP - 114

EP - 133

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

M1 - 18974

ER -