Abstract
The present work addresses high-performance Ruthenium Oxide (RuO2) electrodes prepared by using a simple pulse electrodeposition method. For the comparison purpose, two different precursors, namely, ruthenium (III) nitrosyl sulphate (RuNS) and ruthenium trichloride (RuCl3), were used in this study. The coatings were subjected to material characterisation such as Field Emission Scanning Electron Microscopy and Energy-Dispersive X-ray Spectroscopy, X-ray diffraction and Transmission electron microscopy as well as electrochemical characterisation such as Cyclic Voltammetry, Electrochemical Impedance Spectroscopy and charge/discharge. The RuNS–RuO2 coating exhibited excellent specific capacitance (1724 F/g at 5 A/g) with a remarkable rate capability. This value is significantly higher (52%) than the value obtained for RuCl3–RuO2 electrode material at 5 A/g. The findings provide valuable information on the potential use of RuNS as a precursor for synthesising RuO2 and pulse electrodeposition process to produce electrodes for supercapacitors.
| Original language | English |
|---|---|
| Pages (from-to) | 1-7 |
| Number of pages | 7 |
| Journal | Surface Engineering |
| DOIs | |
| Publication status | Accepted/In press - Jan 23 2018 |
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Keywords
- potentiostatic pulse deposition
- RuCl
- RuO
- ruthenium (III) nitrosyl sulphate
- specific capacitance
- Supercapacitor
ASJC Scopus subject areas
- Condensed Matter Physics
- Surfaces and Interfaces
- Surfaces, Coatings and Films
- Materials Chemistry
Cite this
Pulse electrodeposited RuO2 electrodes for high-performance supercapacitor applications. / Arunachalam, R.; Prataap, R. K.Vishnu; Pavul Raj, R.; Mohan, S.; Vijayakumar, J.; Péter, L.; Al Ahmad, Mahmoud.
In: Surface Engineering, 23.01.2018, p. 1-7.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Pulse electrodeposited RuO2 electrodes for high-performance supercapacitor applications
AU - Arunachalam, R.
AU - Prataap, R. K.Vishnu
AU - Pavul Raj, R.
AU - Mohan, S.
AU - Vijayakumar, J.
AU - Péter, L.
AU - Al Ahmad, Mahmoud
PY - 2018/1/23
Y1 - 2018/1/23
N2 - The present work addresses high-performance Ruthenium Oxide (RuO2) electrodes prepared by using a simple pulse electrodeposition method. For the comparison purpose, two different precursors, namely, ruthenium (III) nitrosyl sulphate (RuNS) and ruthenium trichloride (RuCl3), were used in this study. The coatings were subjected to material characterisation such as Field Emission Scanning Electron Microscopy and Energy-Dispersive X-ray Spectroscopy, X-ray diffraction and Transmission electron microscopy as well as electrochemical characterisation such as Cyclic Voltammetry, Electrochemical Impedance Spectroscopy and charge/discharge. The RuNS–RuO2 coating exhibited excellent specific capacitance (1724 F/g at 5 A/g) with a remarkable rate capability. This value is significantly higher (52%) than the value obtained for RuCl3–RuO2 electrode material at 5 A/g. The findings provide valuable information on the potential use of RuNS as a precursor for synthesising RuO2 and pulse electrodeposition process to produce electrodes for supercapacitors.
AB - The present work addresses high-performance Ruthenium Oxide (RuO2) electrodes prepared by using a simple pulse electrodeposition method. For the comparison purpose, two different precursors, namely, ruthenium (III) nitrosyl sulphate (RuNS) and ruthenium trichloride (RuCl3), were used in this study. The coatings were subjected to material characterisation such as Field Emission Scanning Electron Microscopy and Energy-Dispersive X-ray Spectroscopy, X-ray diffraction and Transmission electron microscopy as well as electrochemical characterisation such as Cyclic Voltammetry, Electrochemical Impedance Spectroscopy and charge/discharge. The RuNS–RuO2 coating exhibited excellent specific capacitance (1724 F/g at 5 A/g) with a remarkable rate capability. This value is significantly higher (52%) than the value obtained for RuCl3–RuO2 electrode material at 5 A/g. The findings provide valuable information on the potential use of RuNS as a precursor for synthesising RuO2 and pulse electrodeposition process to produce electrodes for supercapacitors.
KW - potentiostatic pulse deposition
KW - RuCl
KW - RuO
KW - ruthenium (III) nitrosyl sulphate
KW - specific capacitance
KW - Supercapacitor
UR - http://www.scopus.com/inward/record.url?scp=85040986249&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85040986249&partnerID=8YFLogxK
U2 - 10.1080/02670844.2018.1426408
DO - 10.1080/02670844.2018.1426408
M3 - Article
AN - SCOPUS:85040986249
SP - 1
EP - 7
JO - Surface Engineering
JF - Surface Engineering
SN - 0267-0844
ER -