Pseudopotential method for the thermodynamic properties of liquid alkali metals

R. N. Singh, V. N. Singh

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A pseudopotential method has been considered to study the enthalpy and compressibility of liquid alkali metals (Na, K, Rb and Cs) as a function of temperature. The diameters of the hard sphere reference system were determined by minimising the Helmholtz free energy to ensure thermodynamic stability. The enthalpy, which depends weakly on temperature, has been successfully explained. The investigation suggests that the structure dependent part of energy is sufficient to explain the compressibility of liquid alkali metals near and above the melting temperatures.

Original languageEnglish
Pages (from-to)235-243
Number of pages9
JournalPhysics and Chemistry of Liquids
Volume22
Issue number4
DOIs
Publication statusPublished - Jan 1 1991

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Keywords

  • compressibility
  • Enthalpy
  • stability

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Condensed Matter Physics

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